Racemic and chiral structures of banana-shaped smectic liquid crystals viewed as one-dimensional piezoelectric crystals
文献类型:期刊论文
作者 | Wu, CX; Yamazaki, Y; Zhong-can, OY; Wu, CX , Xiamen Univ, Dept Phys, Xiamen 361005, Peoples R China. |
刊名 | JOURNAL OF CHEMICAL PHYSICS
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出版日期 | 2001 |
卷号 | 115期号:13页码:6204-6209 |
关键词 | Bent-core Molecules Ac Phase-change Achiral Molecules 2nd-harmonic Generation Spectroscopy Order |
ISSN号 | 0021-9606 |
英文摘要 | A smectic liquid-crystal phase formed by achiral banana-shaped molecules (C-B2) is studied as one-dimensional piezoelectric crystals with fluidity of tilted-C-2V anisotropy in the other two spatial dimensions. Variation of the elastic-piezoelectric free energy of the system predicts the existence of racemic (R), left-, and right-handed chiral (H) antiferroelectric equilibrium structures, a result in agreement with the observation by Link [Science 278, 1924 (1997)]. The electric-field-induced ferroelectric state is shown to be a special C-2 symmetry, which confirms the measurements by optical second harmonic generation in a C-B2 by Macdonald [Phys. Rev. Lett. 81, 4408 (1998)]. The hysteresis loop of switching polarization is also discussed, and the molecular tilt angle dependence of spontaneous polarization is obtained as a function of the elastic and the piezoelectric constants. (C) 2001 American Institute of Physics. |
学科主题 | Physics |
URL标识 | 查看原文 |
WOS记录号 | WOS:000171015100055 |
公开日期 | 2012-08-29 |
源URL | [http://ir.itp.ac.cn/handle/311006/13655] ![]() |
专题 | 理论物理研究所_理论物理所1978-2010年知识产出 |
通讯作者 | Wu, CX , Xiamen Univ, Dept Phys, Xiamen 361005, Peoples R China. |
推荐引用方式 GB/T 7714 | Wu, CX,Yamazaki, Y,Zhong-can, OY,et al. Racemic and chiral structures of banana-shaped smectic liquid crystals viewed as one-dimensional piezoelectric crystals[J]. JOURNAL OF CHEMICAL PHYSICS,2001,115(13):6204-6209. |
APA | Wu, CX,Yamazaki, Y,Zhong-can, OY,&Wu, CX , Xiamen Univ, Dept Phys, Xiamen 361005, Peoples R China..(2001).Racemic and chiral structures of banana-shaped smectic liquid crystals viewed as one-dimensional piezoelectric crystals.JOURNAL OF CHEMICAL PHYSICS,115(13),6204-6209. |
MLA | Wu, CX,et al."Racemic and chiral structures of banana-shaped smectic liquid crystals viewed as one-dimensional piezoelectric crystals".JOURNAL OF CHEMICAL PHYSICS 115.13(2001):6204-6209. |
入库方式: OAI收割
来源:理论物理研究所
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