Communication: Probing the existence of partially arrested states in ionic liquids
文献类型：期刊论文
| 作者 | Ramirez-Gonzalez, PE; Sanchez-Diaz, LE; Medina-Noyola, M; Wang, YT ; Ramirez-Gonzalez, PE (reprint author), Univ Autonoma San Luis Potosi, CONACYT Inst Fis Manuel Sandoval Vallarta, Alvaro Obregon 64, San Luis Potosi 78000, Slp, Mexico.
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| 刊名 | JOURNAL OF CHEMICAL PHYSICS
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| 出版日期 | 2016 |
| 卷号 | 145期号:19页码:191101 |
| DOI | http://dx.doi.org/10.1063/1.4967518 |
| 英文摘要 | The recent predictions of the self-consistent generalized Langevin equation theory, describing the existence of unusual partially arrested states in the context of ionic liquids, were probed using all-atom molecular dynamics simulations of a room-temperature ionic liquid. We have found a slower diffusion of the smaller anions compared with the large cations for a wide range of temperatures. The arrest mechanism consists on the formation of a strongly repulsive glass by the anions, stabilized by the long range electrostatic potential. The diffusion of the less repulsive cations occurs through the holes left by the small particles. All of our observations in the simulated system coincide with the theoretical picture. Published by AIP Publishing. |
| 学科主题 | Chemistry ; Physics |
| 语种 | 英语 |
| 源URL | [http://ir.itp.ac.cn/handle/311006/21480]  |
| 专题 | 理论物理研究所_理论物理所1978-2010年知识产出 |
| 通讯作者 | Ramirez-Gonzalez, PE (reprint author), Univ Autonoma San Luis Potosi, CONACYT Inst Fis Manuel Sandoval Vallarta, Alvaro Obregon 64, San Luis Potosi 78000, Slp, Mexico. |
| 推荐引用方式 GB/T 7714 | Ramirez-Gonzalez, PE,Sanchez-Diaz, LE,Medina-Noyola, M,et al. Communication: Probing the existence of partially arrested states in ionic liquids[J]. JOURNAL OF CHEMICAL PHYSICS,2016,145(19):191101. |
| APA | Ramirez-Gonzalez, PE,Sanchez-Diaz, LE,Medina-Noyola, M,Wang, YT,&Ramirez-Gonzalez, PE .(2016).Communication: Probing the existence of partially arrested states in ionic liquids.JOURNAL OF CHEMICAL PHYSICS,145(19),191101. |
| MLA | Ramirez-Gonzalez, PE,et al."Communication: Probing the existence of partially arrested states in ionic liquids".JOURNAL OF CHEMICAL PHYSICS 145.19(2016):191101. |
入库方式： OAI收割
来源：理论物理研究所
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