Polymer precursor synthesis of TaC-SiC ultrahigh temperature ceramic nanocomposites
文献类型：期刊论文
| 作者 | An PF(安鹏飞); An, PF; Ye, L; Lu, Y; Zhao, T; Chen, FH; Qiu, WF |
| 刊名 | RSC ADVANCES
 |
| 出版日期 | 2016 |
| 卷号 | 6期号:91页码:88770-88776 |
| DOI | 10.1039/c6ra17723a |
| 英文摘要 | TaC-SiC ultrahigh temperature ceramic nanocomposites were prepared by cross-linking and subsequent pyrolysis of a novel soluble blend precursor in argon atmosphere. The precursor was synthesized by blending polycarbosilane (PCS) with polytantaloxane (PT). The geometry of metal-ligand interaction of polymer PT was determined by the X-ray absorption fine structure (XAFS). The prepared ceramic nanomaterials were investigated with respect to their chemical and phase composition, by means of FTIR, TG, X-ray diffraction (XRD), Micro-Raman spectroscopy, scanning electron microscopy (SEM) and high-resolution transmission electron microscopy (HR-TEM). Annealing experiments of the TaC-SiC samples at temperatures in the range of 1000-1800 degrees C showed conversion into nanostructured ultrahigh temperature ceramic composites with a trace amount of free carbon. The average grain sizes of the precursor-derived TaC and SiC ceramics were both less than 50 nm. Ta, Si and C elements were homogeneously distributed in the sample at the submicron scale. |
| 语种 | 英语 |
| WOS记录号 | WOS:000384571800108 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/260335]  |
| 专题 | 中国科学院高能物理研究所 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | An PF,An, PF,Ye, L,et al. Polymer precursor synthesis of TaC-SiC ultrahigh temperature ceramic nanocomposites[J]. RSC ADVANCES,2016,6(91):88770-88776. |
| APA | 安鹏飞.,An, PF.,Ye, L.,Lu, Y.,Zhao, T.,...&Qiu, WF.(2016).Polymer precursor synthesis of TaC-SiC ultrahigh temperature ceramic nanocomposites.RSC ADVANCES,6(91),88770-88776. |
| MLA | 安鹏飞,et al."Polymer precursor synthesis of TaC-SiC ultrahigh temperature ceramic nanocomposites".RSC ADVANCES 6.91(2016):88770-88776. |
入库方式： OAI收割
来源：高能物理研究所
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