The status of molybdenum ions in the lead dioxide-lead glasses and vitroceramics
文献类型：期刊论文
| 作者 | Suciu, RC; Rada, M; Culea, E; Biris, A; Rada, S; Leostean, C; Suciu, M; Marian, I; Wu, ZH; Jing, Z |
| 刊名 | JOURNAL OF NON-CRYSTALLINE SOLIDS
 |
| 出版日期 | 2016 |
| 卷号 | 453页码:36-41 |
| 关键词 | xMoO(3)center dot(100-x)[4PbO(2)center dot Pb] glasses and vitroceramics Pb2MoO5 XRD SEM Raman Photoluminescence and XPS spectroscopies |
| DOI | 10.1016/j.jnoncrysol.2016.09.024 |
| 文献子类 | 期刊论文 |
| 英文摘要 | Glasses and vitroceramics in the xMoO(3)center dot(100 - x)[4PbO(2)center dot Pb] system with x = 5-50 mol%MoO3 were prepared by melt quenching method. The influence of MoO3 content on optical properties and structure of the 4PbO(2)center dot Pb host network was investigated using X-ray diffraction (XRD), scanning electron microscopy (SEM), Raman, photofluorescence and X-ray photoelectron (XPS) spectroscopies. The X-ray patterns show the presence of a small amount of Pb2MoO5 crystalline phase in the sample with x = 40 mol%MoO3. By increasing of MoO3 content up to 50 mol% MoO3, Pb2MoO5 and tetragonal PbO crystalline phases were detected. Raman data show the bending modes of the O-Pb-O linkages which allow the intercalation of [PbO4] structural units, isolated [MoO4] and deformed [MoO6] structural units as basic structural units formed by lead and molybdenum atoms. The photofluorescence spectroscopy data shows the transitions of Mo+5 and Pb2+ ions. According to the XPS data, the vitroceramic network contains mainly [MoO4] tetrahedral units and small amounts of [MoO6] octahedral units. (C) 2016 Elsevier B.V. All rights reserved. |
| WOS关键词 | X-RAY-DIFFRACTION ; ELECTRONIC-STRUCTURE ; PB2MOO5 ; SPECTROSCOPY ; CRYSTAL ; PBMOO4 ; PBO ; PROGRAM ; SURFACE ; SYSTEM |
| 语种 | 英语 |
| WOS记录号 | WOS:000388057600006 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/260362]  |
| 专题 | 中国科学院高能物理研究所 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Suciu, RC,Rada, M,Culea, E,et al. The status of molybdenum ions in the lead dioxide-lead glasses and vitroceramics[J]. JOURNAL OF NON-CRYSTALLINE SOLIDS,2016,453:36-41. |
| APA | Suciu, RC.,Rada, M.,Culea, E.,Biris, A.,Rada, S.,...&张静.(2016).The status of molybdenum ions in the lead dioxide-lead glasses and vitroceramics.JOURNAL OF NON-CRYSTALLINE SOLIDS,453,36-41. |
| MLA | Suciu, RC,et al."The status of molybdenum ions in the lead dioxide-lead glasses and vitroceramics".JOURNAL OF NON-CRYSTALLINE SOLIDS 453(2016):36-41. |
入库方式： OAI收割
来源：高能物理研究所
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