Atomic hydrogenation-induced paramagnetic-ferromagnetic transition in zinc ferrite
文献类型：期刊论文
| 作者 | Xiang, QY; Wu, D; Bai, Y; Yan, K; Yao, WQ; Zhang, L; Zhang, J; Cao, JL; Zhang J(张静) |
| 刊名 | CERAMICS INTERNATIONAL
 |
| 出版日期 | 2016 |
| 卷号 | 42期号:15页码:16882-16887 |
| 关键词 | Zinc ferrite Atomic hydrogenation Magnetic transition X-ray absorption fine structure |
| DOI | 10.1016/j.ceramint.2016.07.185 |
| 文献子类 | 期刊论文 |
| 英文摘要 | A paramagnetic-ferromagnetic transition was observed in normal spinel zinc ferrite (ZnFe2O4) during atomic hydrogenation at room temperature. Magnetic measurements showed enhanced ferromagnetic property with increasing hydrogenation time. The hydrogenated ZnFe2O4 has normal spinel structure according to X-ray diffraction (XRD) and Raman analyses. Iron hydride was found from the XRD and X-ray absorption fine structure results. No A-B site ions exchange was observed in the x-ray absorption spectra while the atomic distances of Fe-O, Zn-O, Fe-Fe, Zn-Zn and Fe-Zn coordinations were reduced. A hybrid of Fe2+ and Feat in hydrogenated ZnFe2O4 can be further revealed through deconvolution of x-ray absorption near edge structure. The paramagnetic-ferromagnetic transition and enhanced ferromagnetic property were mainly due to the formation of iron hydride and the B-site super-exchange interactions of Fe2+ and Fe3+. (C) 2016 Elsevier Ltd and Techna Group S.r.l. All rights reserved. |
| WOS关键词 | MAGNETIC-PROPERTIES ; TEMPERATURE ; TIO2 ; NANOPARTICLES ; CONDUCTIVITY |
| 语种 | 英语 |
| WOS记录号 | WOS:000384784100059 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/260363]  |
| 专题 | 中国科学院高能物理研究所 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Xiang, QY,Wu, D,Bai, Y,et al. Atomic hydrogenation-induced paramagnetic-ferromagnetic transition in zinc ferrite[J]. CERAMICS INTERNATIONAL,2016,42(15):16882-16887. |
| APA | Xiang, QY.,Wu, D.,Bai, Y.,Yan, K.,Yao, WQ.,...&张静.(2016).Atomic hydrogenation-induced paramagnetic-ferromagnetic transition in zinc ferrite.CERAMICS INTERNATIONAL,42(15),16882-16887. |
| MLA | Xiang, QY,et al."Atomic hydrogenation-induced paramagnetic-ferromagnetic transition in zinc ferrite".CERAMICS INTERNATIONAL 42.15(2016):16882-16887. |
入库方式： OAI收割
来源：高能物理研究所
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