Loading Actinides in Multilayered Structures for Nuclear Waste Treatment: The First Case Study of Uranium Capture with Vanadium Carbide MXene
文献类型：期刊论文
| 作者 | Yuan, LY; Chen, K; Zhang, YJ; Wang L(王琳) ; Yuan LY(袁立永); Zhang YJ(张玉娟); Zheng LR(郑黎荣); Deng, QH; Zhang J(张静); Chai ZF(柴之芳)
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| 刊名 | ACS APPLIED MATERIALS & INTERFACES
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| 出版日期 | 2016 |
| 卷号 | 8期号:25页码:16396 |
| 关键词 | MXene vanadium carbide actinide sorption uranium DFT calculation EXAFS |
| DOI | 10.1021/acsami.6b02989 |
| 通讯作者 | 石伟群 |
| 英文摘要 | Efficient nuclear waste treatment and environmental management are important hurdles that need to be overcome if nuclear energy is to become more widely used. Herein, we demonstrate the first case of using two-dimensional (2D) multilayered V2CTx nanosheets prepared by HF etching of V2AlC to remove actinides from aqueous solutions. The V2CTx material is found to be a highly efficient uranium (U(VI)) sorbent, evidenced by a high uptake capacity of 174 mg g(-1), fast sorption kinetics, and desirable selectivity. Fitting of the sorption isotherm indicated that the sorption followed a heterogeneous adsorption model, most probably due to the presence of heterogeneous adsorption sites. Density functional theory calculations, in combination with X-ray absorption fine structure characterizations, suggest that the uranyl ions prefer to coordinate with hydroxyl groups bonded to the V-sites of the nanosheets via forming bidentate inner-sphere complexes. |
| 语种 | 英语 |
| WOS记录号 | WOS:000378984800061 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/261063]  |
| 专题 | 高能物理研究所_院士 高能物理研究所_多学科研究中心 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Yuan, LY,Chen, K,Zhang, YJ,et al. Loading Actinides in Multilayered Structures for Nuclear Waste Treatment: The First Case Study of Uranium Capture with Vanadium Carbide MXene[J]. ACS APPLIED MATERIALS & INTERFACES,2016,8(25):16396. |
| APA | Yuan, LY.,Chen, K.,Zhang, YJ.,王琳.,袁立永.,...&Wang, L.(2016).Loading Actinides in Multilayered Structures for Nuclear Waste Treatment: The First Case Study of Uranium Capture with Vanadium Carbide MXene.ACS APPLIED MATERIALS & INTERFACES,8(25),16396. |
| MLA | Yuan, LY,et al."Loading Actinides in Multilayered Structures for Nuclear Waste Treatment: The First Case Study of Uranium Capture with Vanadium Carbide MXene".ACS APPLIED MATERIALS & INTERFACES 8.25(2016):16396. |
入库方式： OAI收割
来源：高能物理研究所
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