Small size Mo2C nanocrystal coupled with reduced graphene oxide enhance the electrochemical activity of palladium nanoparticles towards methanol oxidation reaction
文献类型:期刊论文
作者 | He CY(何春勇); Qiu, YF; Shen, PK; He, GQ; Tao, JZ; He, CY; Tao JZ(陶举洲) |
刊名 | CATALYSIS SCIENCE & TECHNOLOGY
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出版日期 | 2016 |
卷号 | 6期号:19页码:7316-7322 |
DOI | 10.1039/c6cy01299j |
通讯作者 | 何春勇 ; 陶举洲 |
英文摘要 | A small-sized Mo2C nanoparticle on reduced graphene oxide (RGO) nanosheet hybrid (Mo2C-RGO) was applied as a co-catalyst to Pd nanoparticles to form a highly dispersed heterogeneous catalyst (Pd/Mo2C-RGO). Compared to Pd/C, Pd/Mo2C-RGO exhibits significantly enhanced MOR activity; the mass activity of Pd/Mo2C-RGO is 1502 mA mg(Pd)(-1), about 2.5 times that of Pd/C (599 mA mg(Pd)(-1)), and the specific activity (j(k)) of Pd/Mo2C-RGO is 1.59 mA cm(-2) at -0.2 V (vs. Hg/HgO), which is about twice that of Pd/C (0.78 mA cm(-2)). In addition, the resistance to poisonous CO-like intermediates and the durability of Pd/Mo2C-RGO are also remarkably improved. |
学科主题 | Chemistry |
语种 | 英语 |
WOS记录号 | WOS:000384876400033 |
源URL | [http://ir.ihep.ac.cn/handle/311005/260215] ![]() |
专题 | 高能物理研究所_东莞分部 |
作者单位 | 中国科学院高能物理研究所 |
推荐引用方式 GB/T 7714 | He CY,Qiu, YF,Shen, PK,et al. Small size Mo2C nanocrystal coupled with reduced graphene oxide enhance the electrochemical activity of palladium nanoparticles towards methanol oxidation reaction[J]. CATALYSIS SCIENCE & TECHNOLOGY,2016,6(19):7316-7322. |
APA | 何春勇.,Qiu, YF.,Shen, PK.,He, GQ.,Tao, JZ.,...&陶举洲.(2016).Small size Mo2C nanocrystal coupled with reduced graphene oxide enhance the electrochemical activity of palladium nanoparticles towards methanol oxidation reaction.CATALYSIS SCIENCE & TECHNOLOGY,6(19),7316-7322. |
MLA | 何春勇,et al."Small size Mo2C nanocrystal coupled with reduced graphene oxide enhance the electrochemical activity of palladium nanoparticles towards methanol oxidation reaction".CATALYSIS SCIENCE & TECHNOLOGY 6.19(2016):7316-7322. |
入库方式: OAI收割
来源:高能物理研究所
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