Determination of U-236 in environmental samples by single extraction chromatography coupled to triple-quadrupole inductively coupled plasma-mass spectrometry
文献类型：期刊论文
| 作者 | Yang GS(杨国胜); Yang, GS; Tazoe, H; Yamada, M |
| 刊名 | ANALYTICA CHIMICA ACTA
 |
| 出版日期 | 2016 |
| 卷号 | 944页码:44 |
| 关键词 | U-236 activity U-236/U-238 Triple-quadrupole inductively coupled plasma-mass spectrometry Soil Fukushima Daiichi nuclear power plant accident |
| DOI | 10.1016/j.aca.2016.09.033 |
| 英文摘要 | In order to measure trace U-236 and U-236/U-238 in environmental samples with a high matrix effect, a novel and simple method was developed that makes the digestion and purification procedures compatible with advanced triple-quadrupole inductively coupled plasma-mass spectrometry. A total dissolution of sample with HF + HNO3 + HClO4 was followed by chromatographic separation with a single resin column containing normal type DGA resin (N, N, N', N'-tetra-n-octyldiglycolamide) as the extractant system. The analytical accuracy and precision of U-236/U-238 ratios, measured as (UO+)-U-236-O-16/(UO+)-U-238-O-16, were examined by using the reference materials IAEA-135, IAEA-385, IAEA-447, and JSAC 0471. The low method detection limit (3.50 x 10(-6) Bq kg(-1)) makes it possible to perform routine monitoring of environmental U-236 due to global fallout combined with the Fukushima Daiichi Nuclear Power Plant accident fallout (> 10(-5) Bq kg(-1)). Finally, the developed method was successfully applied to measure U-236/U-238 ratios and U-236 activities in soil samples contaminated by the accident. The low U-236/U-238 atom ratios ((1.50 -13.5) x 10(-8)) and U-236 activities ((2.25-14.1) x 10(-2) mBq kg(-1)) indicate U-236 contamination was mainly derived from global fallout in the examined samples. (C) 2016 Elsevier B.V. All rights reserved. |
| WOS记录号 | WOS:000385841200005 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/260513]  |
| 专题 | 高能物理研究所_核技术应用研究中心 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Yang GS,Yang, GS,Tazoe, H,et al. Determination of U-236 in environmental samples by single extraction chromatography coupled to triple-quadrupole inductively coupled plasma-mass spectrometry[J]. ANALYTICA CHIMICA ACTA,2016,944:44. |
| APA | 杨国胜,Yang, GS,Tazoe, H,&Yamada, M.(2016).Determination of U-236 in environmental samples by single extraction chromatography coupled to triple-quadrupole inductively coupled plasma-mass spectrometry.ANALYTICA CHIMICA ACTA,944,44. |
| MLA | 杨国胜,et al."Determination of U-236 in environmental samples by single extraction chromatography coupled to triple-quadrupole inductively coupled plasma-mass spectrometry".ANALYTICA CHIMICA ACTA 944(2016):44. |
入库方式： OAI收割
来源：高能物理研究所
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