preparation and evaluation of open-tubular capillary electrochromatography column with the poly (amidoamine) (pamam) dendrimers as bonded stationary phase
文献类型：期刊论文
| 作者 | Zhang ZS ; Yang Ye |
| 刊名 | Chemical Journal of Chinese Universities-chinese
 |
| 出版日期 | 2006 |
| 卷号 | 27期号:1页码:47-51 |
| 关键词 | dendrimer macromolecule poly (amidoamine) (PAMAM) open-tubular capillary electrochromatography column bonded stationary phase DENDRITIC POLYMERS |
| 通讯作者 | Yang, Y (通讯作者), Beijing Univ Chem Technol, Sch Sci, Beijing 100029, Peoples R China |
| 收录类别 | SCI |
| 公开日期 | 2010-08-23 |
| 附注 | The objective of our study is to explore the potential of poly(amidoamine) (PAMAM) dendrimers as a bonded stationary phase in open tubular capillary electrochromatography(CEC). 1G, 2G and 3G poly(amidoamine) (PAMAM) dendrimers were bonded to the interior wall of silica capillaries through a 3-aminopropyltriethoxysilane linker step by step. The obtained columns were characterized by CEC process. The results show that the electroosmotic flow(EOF) gradually reduced with increasing PAMAM generation. The performances of the column were evaluated by the separation of alanine and praline. The results indicate that the resolution of alanine (Ala) and proline (Pro) was gradually improved with increasing the amount of PAMAM generation. By open-tubular capillary electrochromatography column modified with the 3rd generation PAMAM, the baseline separation of the alanine and proline can be obtained. Five underivatized amino acids, arginine (Arg), alanine (Ala), proline (Pro), histidine (His) and methionine (Met), were successfully separated by OCEC modified with 3G PAMAM and by using UV detection at 200 nm. The reproducibility and stability of the column were satisfactory. |
| 源URL | [http://124.16.136.157/handle/311060/3928]  |
| 专题 | 软件研究所_互联网软件技术实验室 _期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhang ZS,Yang Ye. preparation and evaluation of open-tubular capillary electrochromatography column with the poly (amidoamine) (pamam) dendrimers as bonded stationary phase[J]. Chemical Journal of Chinese Universities-chinese,2006,27(1):47-51. |
| APA | Zhang ZS,&Yang Ye.(2006).preparation and evaluation of open-tubular capillary electrochromatography column with the poly (amidoamine) (pamam) dendrimers as bonded stationary phase.Chemical Journal of Chinese Universities-chinese,27(1),47-51. |
| MLA | Zhang ZS,et al."preparation and evaluation of open-tubular capillary electrochromatography column with the poly (amidoamine) (pamam) dendrimers as bonded stationary phase".Chemical Journal of Chinese Universities-chinese 27.1(2006):47-51. |
入库方式： OAI收割
来源：软件研究所
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