A novel direct conversion of primary amides to their corresponding methyl esters
文献类型：期刊论文
| 作者 | Li, Liang-Chun; Ren, Jie; Liao, Tou-Gen; Jiang, Ju-Xing; Zhu, Hua-Jie |
| 刊名 | EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2007-02-01 |
| 期号 | 6页码:1026-1030 |
| 关键词 | Amides Esters Reaction Mechanisms Density Functional Calculations |
| ISSN号 | 1434-193X |
| DOI | 10.1002/ejoc.200600853 |
| 通讯作者 | hjzhu@mail.kib.ac.cn |
| 文献子类 | Article |
| 英文摘要 | A novel method was used to directly convert aliphatic and aromatic primary amides into their corresponding methyl esters in high yields (up to 99%) under mild reaction conditions. Possible mechanisms were studied at the B3LYP/6-31++G(d,p) level of theory. Formation of the ester proceeded through a rearrangement of the -OMe and -NH2 groups in the RC(O)NHS(O)OMe intermediate in a H+-catalyzed six-membered ring transition state structure. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007). |
| 学科主题 | Chemistry, Organic |
| WOS关键词 | ACIDS ; CARBOXAMIDES ; REAGENTS ; MODEL |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000244578900018 |
| 公开日期 | 2011-12-19 |
| 源URL | [http://ir.kib.ac.cn:8080/handle/151853/2965]  |
| 专题 | 昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室 |
| 作者单位 | 1.CAS, Organ Synth & Nat Prod Lab, Kunming Inst Bot, Kunming 650204, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Liang-Chun,Ren, Jie,Liao, Tou-Gen,et al. A novel direct conversion of primary amides to their corresponding methyl esters[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2007(6):1026-1030. |
| APA | Li, Liang-Chun,Ren, Jie,Liao, Tou-Gen,Jiang, Ju-Xing,&Zhu, Hua-Jie.(2007).A novel direct conversion of primary amides to their corresponding methyl esters.EUROPEAN JOURNAL OF ORGANIC CHEMISTRY(6),1026-1030. |
| MLA | Li, Liang-Chun,et al."A novel direct conversion of primary amides to their corresponding methyl esters".EUROPEAN JOURNAL OF ORGANIC CHEMISTRY .6(2007):1026-1030. |
入库方式： OAI收割
来源：昆明植物研究所
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