Novel taxoids from the Chinese yew Taxus yunnanensis
文献类型：期刊论文
| 作者 | Li, SH ; Zhang, HJ; Niu, XM; Yao, P; Sun, HD; Fong, HHS
|
| 刊名 | TETRAHEDRON
 |
| 出版日期 | 2003 |
| 卷号 | 59期号:1页码:37-45 |
| 关键词 | Taxus Yunnanensis Taxaceae Barks Abeotaxoids Taxane Glycosides Orthoester C-2(20) Epoxide Taxuyunnanines W-z 7-(Beta-xylosyl)-n-methyl-taxol c 10-deacetyl-10-(Beta-glucopyranosyl)-yunnanxane |
| ISSN号 | 0040-4020 |
| 通讯作者 | Zhang, HJ, Univ Illinois, Program Collaborat Res Pharmaceut Sci, Dept Med Chem & Pharmacognosy, Coll Pharm, 833 S Wood St, Chicago, IL 60612 USA |
| 文献子类 | Article |
| 英文摘要 | Six new taxoids, taxuyunnanines W (1), X (2), Y (3), Z (5), 10-deacetyl-10-(beta-glucopyranosyl)-yunnanxane (8), and 7-(beta-xylosyl)-N-methyl-taxol C (10), as well as taxuchin B (4) and yunnanxane (7), have been isolated from the bark of Taxus yunnanensis. Compounds 1 and 2 were characterized as 11 (15-->1)-abeo taxoids containing an orthoester group, which have not been reported from any Taxus plants to date; isolates 3 and 5 are the examples of taxanes having a tetrahydronfuran ring, being reported only for the second time; and 8 is the first natural 6/8/6 skeletal type taxane glucosidic form. This is also the first report of a co-occurrence of xylosidation and N-methylation in a taxane (10). Compound 4 is the only known chlorine-containing taxane found in nature thus far, and is being reported from this plant for the first time. The structures were determined by spectroscopic and chemical means including 1D and 2D NMR spectra. (C) 2002 Elsevier Science Ltd. All rights reserved. |
| 学科主题 | Chemistry, Organic |
| WOS关键词 | TAXANE DITERPENOIDS ; ROOTS ; DERIVATIVES ; CUSPIDATA ; BARK |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000180271500002 |
| 公开日期 | 2012-03-21 |
| 源URL | [http://ir.kib.ac.cn:8080/handle/151853/4606]  |
| 专题 | 昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室 |
| 作者单位 | 1.Univ Illinois, Program Collaborat Res Pharmaceut Sci, Dept Med Chem & Pharmacognosy, Coll Pharm, Chicago, IL 60612 USA 2.Chinese Acad Sci, Lab Phytochem, Kunming Inst Bot, Kunming 650204, Yunnan, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, SH,Zhang, HJ,Niu, XM,et al. Novel taxoids from the Chinese yew Taxus yunnanensis[J]. TETRAHEDRON,2003,59(1):37-45. |
| APA | Li, SH,Zhang, HJ,Niu, XM,Yao, P,Sun, HD,&Fong, HHS.(2003).Novel taxoids from the Chinese yew Taxus yunnanensis.TETRAHEDRON,59(1),37-45. |
| MLA | Li, SH,et al."Novel taxoids from the Chinese yew Taxus yunnanensis".TETRAHEDRON 59.1(2003):37-45. |
入库方式： OAI收割
来源：昆明植物研究所
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