Transition-metal-free dehydrogenation coupling of pyridinium through a self-promoted hydride transfer process
文献类型：期刊论文
| 作者 | Shang, Wenbin1,3; Li, Shanyong1,3; Ding, Yuzhen2; Pan, Zhiqiang2; Tong, Xiaogang2; Xia, Chengfeng1,2 |
| 刊名 | ORGANIC CHEMISTRY FRONTIERS
 |
| 出版日期 | 2017-09-01 |
| 卷号 | 4期号:9页码:1789-1793 |
| 关键词 | C-h Functionalization Hydrogen Evolution Reaction Nickel/lewis Acid Catalysis Visible-light Catalysis Quinoline N-oxides Direct Arylation Bond Activation Selective Alkenylation Grignard-reagents Dft Calculations |
| ISSN号 | 2052-4129 |
| DOI | 10.1039/c7qo00389g |
| 英文摘要 | A transition-metal-free intramolecular cross dehydrogenation coupling reaction of pyridinium was developed. The C(sp(2))-H/C(sp(2))-H coupling reaction involved an unprecedented intermolecular hydride transfer process from the 1,2-dihydropyridine intermediate to another molecule of pyridinium and formed 1,4-dihydropyridine. Unlike the well-known dehydrogenation coupling proceeded under oxidative conditions, this was the first example of the coupling reaction through a substrate self-promoted hydride transfer process. |
| 学科主题 | Chemistry, Organic |
| 语种 | 英语 |
| WOS记录号 | WOS:000408263400014 |
| 源URL | [http://ir.kib.ac.cn/handle/151853/54905]  |
| 专题 | 昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources West Ch, 132 Lanhei Rd, Kunming 650201, Yunnan, Peoples R China 2.Yunnan Univ, Sch Chem Sci & Technol, Minist Educ, Key Lab Med Chem Nat Resources, 2 North Cuihu Rd, Kunming 650091, Yunnan, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shang, Wenbin,Li, Shanyong,Ding, Yuzhen,et al. Transition-metal-free dehydrogenation coupling of pyridinium through a self-promoted hydride transfer process[J]. ORGANIC CHEMISTRY FRONTIERS,2017,4(9):1789-1793. |
| APA | Shang, Wenbin,Li, Shanyong,Ding, Yuzhen,Pan, Zhiqiang,Tong, Xiaogang,&Xia, Chengfeng.(2017).Transition-metal-free dehydrogenation coupling of pyridinium through a self-promoted hydride transfer process.ORGANIC CHEMISTRY FRONTIERS,4(9),1789-1793. |
| MLA | Shang, Wenbin,et al."Transition-metal-free dehydrogenation coupling of pyridinium through a self-promoted hydride transfer process".ORGANIC CHEMISTRY FRONTIERS 4.9(2017):1789-1793. |
入库方式： OAI收割
来源：昆明植物研究所
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