Three Mixed-Alkaline Borates: Na2M2B20O32 (M = Rb, Cs) with Two Interpenetrating Three-Dimensional B-O Networks and Li4Cs4B40O64 with Fundamental Building Block B40O77
文献类型：期刊论文
| 作者 | Abudoureheman, M (Abudoureheman, Maierhaba); Han, SJ (Han, Shujuan) ; Wang, Y (Wang, Ying); Liu, Q (Liu, Qiong); Yang, ZH (Yang, Zhihua); Pan, SL (Pan, Shilie)
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| 刊名 | INORGANIC CHEMISTRY
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| 出版日期 | 2017 |
| 卷号 | 56期号:21页码:13456-13463 |
| ISSN号 | 0020-1669 |
| DOI | 10.1021/acs.inorgchem.7602168 |
| 英文摘要 | Three new mixed-alkaline borates Na2M2B20O33 (M = Rb, Cs) and Li4Cs4B40O64 with unique structures were synthesized by the spontaneous nucleation method, and their structures were determined by single-crystal X-ray diffraction. The B-O networks of Na2M2B20O32 (M = Rb, Cs) are constructed by two independent interpenetrating three-dimensional (3D) frameworks, which is the first case in anhydrous mixed-alkaline borate systems. In addition, Li4Cs4B40O64 shows high B-O polymerization with a new fundamental building block B40O77. Meanwhile, detailed structure comparisons containing the cation effect on the framework have been discussed. UV-vis-NIR diffuse reflectance spectra and the infrared spectra were measured. The band structures and the density of states were performed using, density functional theory calculation. |
| WOS记录号 | WOS:000414820100086 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/5080]  |
| 专题 | 新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室 新疆理化技术研究所_材料物理与化学研究室 |
| 通讯作者 | Han, SJ (Han, Shujuan); Pan, SL (Pan, Shilie) |
| 作者单位 | 1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China 2.Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Abudoureheman, M ,Han, SJ ,Wang, Y ,et al. Three Mixed-Alkaline Borates: Na2M2B20O32 (M = Rb, Cs) with Two Interpenetrating Three-Dimensional B-O Networks and Li4Cs4B40O64 with Fundamental Building Block B40O77[J]. INORGANIC CHEMISTRY,2017,56(21):13456-13463. |
| APA | Abudoureheman, M ,Han, SJ ,Wang, Y ,Liu, Q ,Yang, ZH ,&Pan, SL .(2017).Three Mixed-Alkaline Borates: Na2M2B20O32 (M = Rb, Cs) with Two Interpenetrating Three-Dimensional B-O Networks and Li4Cs4B40O64 with Fundamental Building Block B40O77.INORGANIC CHEMISTRY,56(21),13456-13463. |
| MLA | Abudoureheman, M ,et al."Three Mixed-Alkaline Borates: Na2M2B20O32 (M = Rb, Cs) with Two Interpenetrating Three-Dimensional B-O Networks and Li4Cs4B40O64 with Fundamental Building Block B40O77".INORGANIC CHEMISTRY 56.21(2017):13456-13463. |
入库方式： OAI收割
来源：新疆理化技术研究所
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