Chemical Cosubstitution-Oriented Design of Rare-Earth Borates as Potential Ultraviolet Nonlinear Optical Materials
文献类型：期刊论文
| 作者 | Mutailipu, M (Mutailipu, Miriding) ; Xie, ZQ (Xie, Zhiqing); Su, X (Su, Xin); Zhang, M (Zhang, Min); Wang, Y (Wang, Ying); Yang, ZH (Yang, Zhihua); Janjua, MRSA (Janjua, Muhammad Ramzan Saeed Ashraf); Pan, SL (Pan, Shilie)
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| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
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| 出版日期 | 2017 |
| 卷号 | 139期号:50页码:18397-18405 |
| ISSN号 | 0002-7863 |
| DOI | 10.1021/jacs.7b11263 |
| 英文摘要 | A chemical cosubstitution strategy was implemented to design potential ultraviolet (UV) and deep-UV nonlinear optical (NLO) materials. Taking the classic beta-BaB2O4 as a maternal structure, by simultaneously replacing the Ba2+ and [B3O6](3- )units with monovalant (K+), divalent (alkaline earth metal), trivalent (rare-earth metal, Bi3+) ions, and the [B5O10](5- )clusters through two different practical routes, 12 new mixed-metal noncentrosymmetric borates (K7MRE2)-R-II(B5O10)(3) (M-II = Ca, Sr, Ba, K/RE0.5; RE = Y, Lu, Gd) as well as (K7MBi2)-Bi-II(B5O10)(3) (M-II = Pb, Sr) were successfully designed and synthesized as high-quality single crystals. The selected K7CaY2(B5O10)(3), K7SrY2(B5O10)(3), and K7BaY2(B5O10)(3 )compounds were subjected to experimental and theoretical characterizations. They all exhibit suitable second-harmonic generation (SHG) responses, as large as that of commercial KH2PO4 (KDP), and also exhibit short UV cutoff edges. These results confirm the feasibility of this chemical cosubstitution strategy to design NLO materials and that the three selected crystals may have potential application as UV NLO materials. |
| WOS记录号 | WOS:000418783600042 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/5118]  |
| 专题 | 新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室 新疆理化技术研究所_材料物理与化学研究室 |
| 通讯作者 | Zhang, M (Zhang, Min); Wang, Y (Wang, Ying); Pan, SL (Pan, Shilie) |
| 作者单位 | 1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Funct Mat & Devices Special Environm, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China 2.Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Yili Normal Univ, Coll Phys Sci & Technol, Xinjiang Lab Phase Transit & Microstruct Condensed, Yining 835000, Xinjiang, Peoples R China 5.King Fahd Univ Petr & Minerals, Chem Dept, Dhahran 31261, Saudi Arabia |
| 推荐引用方式 GB/T 7714 | Mutailipu, M ,Xie, ZQ ,Su, X ,et al. Chemical Cosubstitution-Oriented Design of Rare-Earth Borates as Potential Ultraviolet Nonlinear Optical Materials[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2017,139(50):18397-18405. |
| APA | Mutailipu, M .,Xie, ZQ .,Su, X .,Zhang, M .,Wang, Y .,...&Pan, SL .(2017).Chemical Cosubstitution-Oriented Design of Rare-Earth Borates as Potential Ultraviolet Nonlinear Optical Materials.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,139(50),18397-18405. |
| MLA | Mutailipu, M ,et al."Chemical Cosubstitution-Oriented Design of Rare-Earth Borates as Potential Ultraviolet Nonlinear Optical Materials".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 139.50(2017):18397-18405. |
入库方式： OAI收割
来源：新疆理化技术研究所
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