Selective oxidation of benzylic, allylic and propargylic alcohols using dirhodium(II) tetraamidinate as catalyst and aqueous tert-butyl hydroperoxide as oxidant
文献类型：期刊论文
| 作者 | Wusiman, A (Wusiman, Abudureheman); Lu, CD (Lu, Chong-Dao) |
| 刊名 | APPLIED ORGANOMETALLIC CHEMISTRY
 |
| 出版日期 | 2015 |
| 卷号 | 29期号:4页码:254-258 |
| 关键词 | Dirhodium(Ii) Catalyst Oxidation Alcohols Tert-butyl Hydroperoxide |
| DOI | 10.1002/aoc.3281 |
| 英文摘要 | We show that the dirhodium(II) tetraamidinate complex Rh-2(Msip)(4) efficiently catalyzes the oxidation of activated secondary alcohols at only 0.1 mol% loading. In this approach, we oxidized various benzylic, allylic and propargylic alcohols to the corresponding carbonyl compounds under mild aqueous conditions using the inexpensive oxidant T-HYDRO (R) (70 wt% aqueous tert-butyl hydroperoxide). |
| WOS记录号 | WOS:000351603700013 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/5167]  |
| 专题 | 新疆理化技术研究所_资源化学研究室 |
| 作者单位 | 1.Xinjiang Normal Univ, Sch Chem & Chem Engn, Urumqi 830054, Peoples R China 2.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wusiman, A ,Lu, CD . Selective oxidation of benzylic, allylic and propargylic alcohols using dirhodium(II) tetraamidinate as catalyst and aqueous tert-butyl hydroperoxide as oxidant[J]. APPLIED ORGANOMETALLIC CHEMISTRY,2015,29(4):254-258. |
| APA | Wusiman, A ,&Lu, CD .(2015).Selective oxidation of benzylic, allylic and propargylic alcohols using dirhodium(II) tetraamidinate as catalyst and aqueous tert-butyl hydroperoxide as oxidant.APPLIED ORGANOMETALLIC CHEMISTRY,29(4),254-258. |
| MLA | Wusiman, A ,et al."Selective oxidation of benzylic, allylic and propargylic alcohols using dirhodium(II) tetraamidinate as catalyst and aqueous tert-butyl hydroperoxide as oxidant".APPLIED ORGANOMETALLIC CHEMISTRY 29.4(2015):254-258. |
入库方式： OAI收割
来源：新疆理化技术研究所
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