A new 12L-hexagonal perovskite Cs4Mg3CaF12: structural transition derived from the partial substitution of Mg2+ with Ca2+
文献类型:期刊论文
作者 | Wang, Z (Wang, Zheng); Jing, Q (Jing, Qun); Zhang, M (Zhang, Min)![]() ![]() ![]() |
刊名 | RSC ADVANCES
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出版日期 | 2014 |
卷号 | 4期号:97页码:54194-54198 |
ISSN号 | 2046-2069 |
DOI | 10.1039/c4ra07819e |
英文摘要 | A new 12L-hexagonal perovskite Cs4Mg3CaF12 was synthesized using an open high-temperature solution method. It crystallizes in the trigonal space group R3m (no. 166) with lattice constants a = 6.2196(9) angstrom, c = 29.812(9) angstrom, Z = 3. Cs4Mg3CaF12 is changed from the cubic phase CsMgF3 by replacing 25% Mg2+ with Ca2+. The changes derived from the substitution and the structural comparison between Cs4Mg3CaF12 and other perovskites are discussed in this paper. Thermal analysis, infrared spectroscopy, and electronic structure calculations were performed on the reported material. |
WOS记录号 | WOS:000344600400008 |
源URL | [http://ir.xjipc.cas.cn/handle/365002/5231] ![]() |
专题 | 新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室 新疆理化技术研究所_材料物理与化学研究室 |
通讯作者 | Zhang, M (Zhang, Min) |
作者单位 | 1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Key Lab Funct Mat & Devices Special Environm, Urumqi 830011, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Z ,Jing, Q ,Zhang, M ,et al. A new 12L-hexagonal perovskite Cs4Mg3CaF12: structural transition derived from the partial substitution of Mg2+ with Ca2+[J]. RSC ADVANCES,2014,4(97):54194-54198. |
APA | Wang, Z ,Jing, Q ,Zhang, M ,Dong, XY ,Pan, SL ,&Yang, ZH .(2014).A new 12L-hexagonal perovskite Cs4Mg3CaF12: structural transition derived from the partial substitution of Mg2+ with Ca2+.RSC ADVANCES,4(97),54194-54198. |
MLA | Wang, Z ,et al."A new 12L-hexagonal perovskite Cs4Mg3CaF12: structural transition derived from the partial substitution of Mg2+ with Ca2+".RSC ADVANCES 4.97(2014):54194-54198. |
入库方式: OAI收割
来源:新疆理化技术研究所
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