Phase Behavior of Tween80/BmimPF(6)/Alcohol/Toluene Systems
文献类型:期刊论文
作者 | Zheng, YJ (Zheng Yong-Jun); Eli, WJ (Eli Wumanjiang); Eli, WJ |
刊名 | ACTA PHYSICO-CHIMICA SINICA
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出版日期 | 2008 |
卷号 | 24期号:11页码:2143-2148 |
关键词 | Microemulsions Ionic Liquids Alcohol Pseudo Ternary Phase Diagram |
DOI | 10.3866/PKU.WHXB20081135 |
英文摘要 | To investigate the influence of different alcohols on the isotropic microemulsion zone of a 1-butyl-3-methylimidazolium hexafluorophosphate (bmimPF(6))/Tween80/toluene systems pseudo ternary phase diagrams of bmimPF(6)/Tween80/alcohol/toluene systems under different conditions were constructed. Alcohols used were C2H5OH n-C4H9OH, n-C6H13OH, n-C8H17OH, n-C10H21OH, and i-C5H11OH. Effects of alcohol type and content on the formation of the microemulsion region were investigated. Phase diagrams showed that the microemulsion domain became larger as the Tween80/alcohol weight ratio increased for i-C5H11OH. Different chain lengths of alcohols affected the magnitude of microemulsion regions and this was also dependent on the alcohol solubility in bmimPF(6). The single-phase microemulsion area decreased as the alcohol chain length increased. The single-phase region of the ethanol-containing system was the largest among the systems studied. Oil-in-ionic liquid (O/IL) microemulsions, bicontinuous microemulsions, and ionic liquid-in-oil (IL/O) microemulsions in isotropic regions were identified by conductivity measurements. Initial increases of conductivity in ionic liquid microemulsions with increased oil content was due to the oil decreasing ion pairs or ions accumulating in the ionic liquid microemulsion thus increasing the number of charge carriers and improving ionic mobility. |
WOS记录号 | WOS:000261204000035 |
源URL | [http://ir.xjipc.cas.cn/handle/365002/5246] ![]() |
专题 | 新疆理化技术研究所_资源化学研究室 |
通讯作者 | Eli, WJ |
作者单位 | 1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zheng, YJ ,Eli, WJ ,Eli, WJ. Phase Behavior of Tween80/BmimPF(6)/Alcohol/Toluene Systems[J]. ACTA PHYSICO-CHIMICA SINICA,2008,24(11):2143-2148. |
APA | Zheng, YJ ,Eli, WJ ,&Eli, WJ.(2008).Phase Behavior of Tween80/BmimPF(6)/Alcohol/Toluene Systems.ACTA PHYSICO-CHIMICA SINICA,24(11),2143-2148. |
MLA | Zheng, YJ ,et al."Phase Behavior of Tween80/BmimPF(6)/Alcohol/Toluene Systems".ACTA PHYSICO-CHIMICA SINICA 24.11(2008):2143-2148. |
入库方式: OAI收割
来源:新疆理化技术研究所
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