Diastereoselective alpha-Sulfenylation of N-tert-Butanesulfinyl Imidates
文献类型：期刊论文
| 作者 | Niu, ST (Niu, Sheng-Tong)[ 1,2 ]; Liu, H (Liu, Hui)[ 1 ]; Xu, YJ (Xu, Yan-Jun)[ 1 ]; Lu, CD (Lu, Chong-Dao)[ 1 ] |
| 刊名 | JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2018 |
| 卷号 | 83期号:17页码:10580-10588 |
| ISSN号 | 0022-3263 |
| DOI | 10.1021/acs.joc.8b01403 |
| 英文摘要 | A diastereoselective alpha-sulfenylation of chiral alpha-aryl/alkyl N-tert-butanesulfinyl imidates has been developed. Suitable sulfur electrophiles can be used as sulfenylating reagents to intercept aza-enolates generated from imidate deprotonation, giving alpha-thiofunctionalized imidates in good yields with high diastereocontrol. This protocol for C-S bond formation can efficiently synthesize enantioenriched 1,2-sulfanyl amine derivatives such as sulconazole. |
| WOS记录号 | WOS:000444364600093 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/5595]  |
| 专题 | 新疆理化技术研究所_省部共建新疆特有药用资源利用重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Key Lab Plant Resources & Chem Arid Zones, Urumqi 830011, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Niu, ST ,Liu, H ,Xu, YJ ,et al. Diastereoselective alpha-Sulfenylation of N-tert-Butanesulfinyl Imidates[J]. JOURNAL OF ORGANIC CHEMISTRY,2018,83(17):10580-10588. |
| APA | Niu, ST ,Liu, H ,Xu, YJ ,&Lu, CD .(2018).Diastereoselective alpha-Sulfenylation of N-tert-Butanesulfinyl Imidates.JOURNAL OF ORGANIC CHEMISTRY,83(17),10580-10588. |
| MLA | Niu, ST ,et al."Diastereoselective alpha-Sulfenylation of N-tert-Butanesulfinyl Imidates".JOURNAL OF ORGANIC CHEMISTRY 83.17(2018):10580-10588. |
入库方式： OAI收割
来源：新疆理化技术研究所
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