Tuning the Solid State Emission of the Carbazole and Cyano-Substituted Tetraphenylethylene by Co-Crystallization with Solvents
文献类型：期刊论文
| 作者 | Wang, Yuancheng1,2; Zhang, Guanxin1; Zhang, Wei1,2; Wang, Xuedong1,2; Wu, Yishi1; Liang, Tongling1; Hao, Xiang1; Fu, Hongbing1; Zhao, Yongsheng1; Zhang, Deqing1 |
| 刊名 | SMALL
 |
| 出版日期 | 2016-12-21 |
| 卷号 | 12期号:47页码:6554-6561 |
| 英文摘要 | Solid state emissive materials with high quantum yields and tunable emissions are desirable for various applications. A new TPE derivative (1) with two carbazole moieties and two cyano groups is reported, which shows typical aggregation induced emission behavior. Four crystals 1a, 1b, 1c, and 1d are obtained after crystallization from N, N-dimethylformamid (DMF), trichloromethane (CHCl3), tetrahydrofuran (THF), and dichloromethane (CH2Cl2), respectively. Crystal structural analyses reveal that (i) molecules of 1 co-crystallize with DMF, CHCl3, THF, and CH2Cl2 in 1a, 1b, 1c, and 1d, respectively, and (ii) conformations of 1 are different within 1a, 1b, 1c, and 1d, and compound 1 within crystal 1a adopts the most twisting conformation. Crystalline solids 1a, 1b, 1c, and 1d exhibit high emission quantum yields up to 0.65, but their emission colors are varied from blue to green. In comparison, the amorphous solid of 1 is yellow-emissive with emission maximum at 542 nm. Moreover, the blue-or green-emissive crystalline solids and the yellow-emissive amorphous solid can be inter-converted by the grinding of crystalline solids and exposure of the amorphous solid to vapors of appropriate solvents. It is also demonstrated that microrods of 1a, 1b, and 1d show typical optical waveguiding behavior. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/37943]  |
| 专题 | 化学研究所_有机固体实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Labs Organ Solids & Photochem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Yuancheng,Zhang, Guanxin,Zhang, Wei,et al. Tuning the Solid State Emission of the Carbazole and Cyano-Substituted Tetraphenylethylene by Co-Crystallization with Solvents[J]. SMALL,2016,12(47):6554-6561. |
| APA | Wang, Yuancheng.,Zhang, Guanxin.,Zhang, Wei.,Wang, Xuedong.,Wu, Yishi.,...&Zhang, Deqing.(2016).Tuning the Solid State Emission of the Carbazole and Cyano-Substituted Tetraphenylethylene by Co-Crystallization with Solvents.SMALL,12(47),6554-6561. |
| MLA | Wang, Yuancheng,et al."Tuning the Solid State Emission of the Carbazole and Cyano-Substituted Tetraphenylethylene by Co-Crystallization with Solvents".SMALL 12.47(2016):6554-6561. |
入库方式： OAI收割
来源：化学研究所
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