Preparation and Spectroscopic Studies of FC(O)SSCl
文献类型：期刊论文
| 作者 | Cozzarin, Melina V.1; Tong, Shengrui2; Ge, Mao-Fa2; Della Vedova, Carlos O.1; Romano, Rosana M.1 |
| 刊名 | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
 |
| 出版日期 | 2016-12-01 |
| 期号 | 36页码:5568-5574 |
| 关键词 | Sulfides Photoelectron Spectroscopy Conformation Analysis Vibrational Spectroscopy Matrix Isolation |
| 英文摘要 | The hitherto unknown FC(O)SSCl molecule has been prepared by the reaction of ClC(O)SSCl with TlF under vacuum conditions. The molecule was characterized by its electron-impact mass spectrum, the IR spectrum of a vapour-phase sample, the Raman spectrum of the liquid, and also the matrix-isolated FTIR spectra. FC(O)SSCl is composed of an equilibrium mixture of two conformers, syn-gauche and anti-gauche, both in the vapour and liquid phases, with an approximate ratio of 80:20. The valence electronic properties of FC(O)SSCl were studied by photoelectron spectroscopy. The first ionization potential was observed at 10.14 eV, and the HOMO was assigned to the nonbonding electron lone pair located on the S atom bonded to the carbonyl group. A decrease in the dihedral angle of the SS bond after ionization was predicted by quantum chemical calculations. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/37951]  |
| 专题 | 化学研究所_分子动态与稳态结构实验室 |
| 作者单位 | 1.Univ Nacl La Plata, Fac Ciencias Exactas, Dept Quim, CEQUINOR,CCT,CONICET La Plata, Blvd 120 1465,CC 962, RA-1900 La Plata, Buenos Aires, Argentina 2.Chinese Acad Sci, State Key Lab Struct Chem Unstable & Stable Speci, BNLMS, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cozzarin, Melina V.,Tong, Shengrui,Ge, Mao-Fa,et al. Preparation and Spectroscopic Studies of FC(O)SSCl[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2016(36):5568-5574. |
| APA | Cozzarin, Melina V.,Tong, Shengrui,Ge, Mao-Fa,Della Vedova, Carlos O.,&Romano, Rosana M..(2016).Preparation and Spectroscopic Studies of FC(O)SSCl.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(36),5568-5574. |
| MLA | Cozzarin, Melina V.,et al."Preparation and Spectroscopic Studies of FC(O)SSCl".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY .36(2016):5568-5574. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。