Bisperylene bisimide based conjugated polymer as electron acceptor for polymer-polymer solar cells
文献类型：期刊论文
| 作者 | Yang, Fan; Li, Cheng; Feng, Gui-tao; Jiang, Xu-dong; Zhang, An-dong; Li, Wei-wei |
| 刊名 | CHINESE JOURNAL OF POLYMER SCIENCE
 |
| 出版日期 | 2017-02-01 |
| 卷号 | 35期号:2页码:239-248 |
| 关键词 | Polymer Solar Cells Conjugated Polymers Electron Acceptor Perylene Bisimide |
| 英文摘要 | Perylene bisimide (PBI) unit has been widely used to design conjugated materials, which can be used as electron acceptor in organic solar cells due to its strong electron-deficient ability. In this work, a conjugated polymer based on PBI dimer as monomer was designed, synthesized, and compared to the conjugated polymer containing single PBI as repeating units. The two conjugated polymers were found to have similar molecular weight, absorption spectra and energy levels. Density functional theory calculation revealed that the PBI dimer-based polymer exhibited highly twisted conjugated backbone due to the large dihedral angle between the two PBI units. The PBI-based polymers as electron acceptor were applied into polymer-polymer solar cells, in which PBI dimer-based polymer solar cells were found to show a high short circuit current density (J (sc) = 11.2 mAa (TM) cm(-2) and a high power conversion efficiency (PCE) of 4.5%. In comparison, the solar cells based on PBI-based polymer acceptor only provided a J (sc) of 7.2 mAa (TM) cm(-2) and PCE of 2.5%. The significantly enhanced PCE in PBI dimer-based solar cells was attributed to the mixed phase in blended thin films, as revealed by atom force microscopy. This study demonstrates that PBI dimer can be used to design polymer acceptors for high performance polymerpolymer solar cells. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38032]  |
| 专题 | 化学研究所_有机固体实验室 |
| 作者单位 | Chinese Acad Sci, Beijing Natl Lab Mol Sci, Key Lab Organ Solids, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Fan,Li, Cheng,Feng, Gui-tao,et al. Bisperylene bisimide based conjugated polymer as electron acceptor for polymer-polymer solar cells[J]. CHINESE JOURNAL OF POLYMER SCIENCE,2017,35(2):239-248. |
| APA | Yang, Fan,Li, Cheng,Feng, Gui-tao,Jiang, Xu-dong,Zhang, An-dong,&Li, Wei-wei.(2017).Bisperylene bisimide based conjugated polymer as electron acceptor for polymer-polymer solar cells.CHINESE JOURNAL OF POLYMER SCIENCE,35(2),239-248. |
| MLA | Yang, Fan,et al."Bisperylene bisimide based conjugated polymer as electron acceptor for polymer-polymer solar cells".CHINESE JOURNAL OF POLYMER SCIENCE 35.2(2017):239-248. |
入库方式： OAI收割
来源：化学研究所
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