Nonfullerene-Acceptor All-Small-Molecule Organic Solar Cells Based on Highly Twisted Perylene Bisimide with an Efficiency of over 6%
文献类型：期刊论文
| 作者 | Xin, Rui1; Feng, Jiajing2; Zeng, Cheng2; Jiang, Wei2; Zhang, Lei1; Meng, Dong2; Ren, Zhongjie1; Wang, Zhaohui2; Yan, Shouke1 |
| 刊名 | ACS APPLIED MATERIALS & INTERFACES
 |
| 出版日期 | 2017-01-25 |
| 卷号 | 9期号:3页码:2739-2746 |
| 关键词 | Nonfullerene All-small-molecule Organic Solar Cells Perylene Bisimide Twisted Conformation Nonfullerene Acceptor Solvent-vapor Annealing |
| 英文摘要 | Two twisted singly linked perylene bisimide (PBI) dimers with chalcogen bridges in the PBI cores, named C4,4-SdiPBI-S and C4,4-SdiPBI-Se, were synthesized as acceptors for nonfullerene all-small-molecule organic solar cells (NF all-SMSCs). A moderate-band-gap small-molecule DR3TBDTT used as the electron donor displayed complementary absorption with C4,4-SdiPBI-S and C4,4-SdiPBI-Se. It was found that solvent-vapor annealing (SVA) played a critical role in the photovoltaic performance in NF all-SMSCs, which improves the crystallinity of the donor and acceptors, promotes the proper phase segregation domain size, and therefore enhances charge transport. The power conversion efficiencies (PCEs) of NF all-SMSC devices based on DR3TBDTT/C4,4-SdiPBI-S and DR3TBDTT/C4,4-SdiPBI-Se increased from 2.52% to 5.81% (J(SC) = 11.12 mA cm(-2), V-OC = 0.91 V, and FF = 57.32%) and from 2.65% to 6.22% (J(SC) = 11.55 mA cm(-2), V-OC = 0.92 V, and FF = 58.72%), respectively, after exposure to chloroform vapor. The best efficiency of 6.22% is one of the highest PCEs for NF all-SMSC-based PBI acceptors so far. The studies illustrate that highly efficient NF all-SMSCs can be achieved by using a PBI acceptor with a suitable SVA process. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38067]  |
| 专题 | 化学研究所_有机固体实验室 |
| 作者单位 | 1.Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Key Lab Organ Solids, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xin, Rui,Feng, Jiajing,Zeng, Cheng,et al. Nonfullerene-Acceptor All-Small-Molecule Organic Solar Cells Based on Highly Twisted Perylene Bisimide with an Efficiency of over 6%[J]. ACS APPLIED MATERIALS & INTERFACES,2017,9(3):2739-2746. |
| APA | Xin, Rui.,Feng, Jiajing.,Zeng, Cheng.,Jiang, Wei.,Zhang, Lei.,...&Yan, Shouke.(2017).Nonfullerene-Acceptor All-Small-Molecule Organic Solar Cells Based on Highly Twisted Perylene Bisimide with an Efficiency of over 6%.ACS APPLIED MATERIALS & INTERFACES,9(3),2739-2746. |
| MLA | Xin, Rui,et al."Nonfullerene-Acceptor All-Small-Molecule Organic Solar Cells Based on Highly Twisted Perylene Bisimide with an Efficiency of over 6%".ACS APPLIED MATERIALS & INTERFACES 9.3(2017):2739-2746. |
入库方式： OAI收割
来源：化学研究所
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