Synthesis and Characterization of Arylenevinylenearylene-Naphthalene Diimide Copolymers as Acceptor in All-Polymer Solar Cells
文献类型：期刊论文
| 作者 | Xue, Lingwei1,2; Yang, Yankang2,3; Bin, Haijun2,3; Zhang, Zhi-Guo2; Zhang, Jing2; Yang, YunXu1; Li, Yongfang2,3 |
| 刊名 | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
 |
| 出版日期 | 2017-05-15 |
| 卷号 | 55期号:10页码:1757-1764 |
| 关键词 | All-polymer Solar Cells J51 Ndi-based Polymer Acceptor N-type Conjugated Polymers |
| 英文摘要 | Two n-type conjugated D-A copolymers, P(TVT-NDI) and P(FVF-NDI) with thienylene-vinylene-thienylene (TVT) or furanylene-vinylene-furanylene (FVF) as donor (D) units and naphthalene diimide (NDI) as the acceptor (A) units, were synthesized by the Stille coupling copolymerization. The two polymers possess good solubility, high thermal stability, and broad absorption bands with absorption edges at 866 nm for P(TVT-NDI) and 886 nm for P(FVF-NDI). The LUMO energy levels of P(TVT-NDI) and P(FVF-NDI) are -3.80 eV and -3.76 eV respectively, so the two polymers are suitable for the application as acceptor in blending with most polymer donor in PSCs based on the energy level matching point of view. All polymer solar cells (all-PSCs) were fabricated with P(TVT-NDI) or P(FVF-NDI) as acceptor and medium bandgap polymer J51 as donor for investigating the photovoltaic performance of the two n-type conjugated polymer acceptors. And higher power conversion efficiency of 6.43% for P(TVT-NDI) and 5.21% for P(FVF-NDI) was obtained. The results indicate that arylenevinylenearylene-naphthalene diimide copolymer are promising polymer acceptor for all-PSCs. (C) 2017 Wiley Periodicals, Inc. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38096]  |
| 专题 | 化学研究所_有机固体实验室 |
| 作者单位 | 1.Univ Sci & Technol Beijing, Sch Chem & Biol Engn, Dept Chem & Chem Engn, Beijing 100083, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, CAS Key Lab Organ Solids, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xue, Lingwei,Yang, Yankang,Bin, Haijun,et al. Synthesis and Characterization of Arylenevinylenearylene-Naphthalene Diimide Copolymers as Acceptor in All-Polymer Solar Cells[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2017,55(10):1757-1764. |
| APA | Xue, Lingwei.,Yang, Yankang.,Bin, Haijun.,Zhang, Zhi-Guo.,Zhang, Jing.,...&Li, Yongfang.(2017).Synthesis and Characterization of Arylenevinylenearylene-Naphthalene Diimide Copolymers as Acceptor in All-Polymer Solar Cells.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,55(10),1757-1764. |
| MLA | Xue, Lingwei,et al."Synthesis and Characterization of Arylenevinylenearylene-Naphthalene Diimide Copolymers as Acceptor in All-Polymer Solar Cells".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 55.10(2017):1757-1764. |
入库方式： OAI收割
来源：化学研究所
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