Fused Nonacyclic Electron Acceptors for Efficient Polymer Solar Cells
文献类型：期刊论文
| 作者 | Dai, Shuixing1,2; Zhao, Fuwen3; Zhang, Qianqian4; Lau, Tsz-Ki5; Li, Tengfei1; Liu, Kuan1; Ling, Qidan2; Wang, Chunru3; Lu, Xinhui5; You, Wei4 |
| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
 |
| 出版日期 | 2017-01-25 |
| 卷号 | 139期号:3页码:1336-1343 |
| 英文摘要 | We design and synthesize four fused-ring electron acceptors based on-6,6,12,12-tetrakis(4-hexylphenyl)-indacenobis(dithieno[3,2-b-2',3'-d]thiophene) as the electron-rich unit and 1,1-dicyanomethylene-3-indanones with 0-2 fluorine substituents as the electron-deficient units. These four molecules exhibit broad (550-850 nm) and strong absorption with high extinction coefficients of (2.1-2.5) x 10(5) M-1 cm(-1). Fluorine substitution downshifts the LUMO energy level, red-shifts the absorption spectrum, and enhances electron mobility. The polymer solar cells based on the fluorinated electron acceptors exhibit power conversion efficiencies as high as 11.5%, much higher than that of their nonfluorinated counterpart (7.7%). We investigate the effects of the fluorine atom number and position on electronic properties, charge transport, film morphology, and photovoltaic properties. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38136]  |
| 专题 | 化学研究所_分子纳米结构与纳米技术实验室 |
| 作者单位 | 1.Peking Univ, Dept Mat Sci & Engn, Key Lab Polymer Chem & Phys, Coll Engn,Minist Educ, Beijing 100871, Peoples R China 2.Fujian Normal Univ, Coll Mat Sci & Engn, Fujian Key Lab Polymer Mat, Fuzhou 350007, Peoples R China 3.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China 4.Univ North Carolina Chapel Hill, Dept Chem, Chapel Hill, NC 27599 USA 5.Chinese Univ Hong Kong, Dept Phys, Hong Kong, Hong Kong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Dai, Shuixing,Zhao, Fuwen,Zhang, Qianqian,et al. Fused Nonacyclic Electron Acceptors for Efficient Polymer Solar Cells[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2017,139(3):1336-1343. |
| APA | Dai, Shuixing.,Zhao, Fuwen.,Zhang, Qianqian.,Lau, Tsz-Ki.,Li, Tengfei.,...&Zhan, Xiaowei.(2017).Fused Nonacyclic Electron Acceptors for Efficient Polymer Solar Cells.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,139(3),1336-1343. |
| MLA | Dai, Shuixing,et al."Fused Nonacyclic Electron Acceptors for Efficient Polymer Solar Cells".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 139.3(2017):1336-1343. |
入库方式： OAI收割
来源：化学研究所
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