Photo-induced Catalytic Asymmetric Free Radical Reactions
文献类型：期刊论文
| 作者 | Wang Dehong; Zhang Long; Luo Sanzhong1 |
| 刊名 | ACTA CHIMICA SINICA
 |
| 出版日期 | 2017-01-15 |
| 卷号 | 75期号:1页码:22-33 |
| 关键词 | Photoredox Catalysis Free Radical Reaction Asymmetric Catalysis Synergistic Catalysis |
| 英文摘要 | Enantioselective control of free radical reactions has eluded organic chemists for decades. Echoed with the renaissance of photo-induced processes, or so called photocatalysis or photoredox catalysis in organic synthesis, photo-induced organic radical chemistry has regained its prominence in developing catalytic asymmetric radical reaction. The generally mild conditions inherited with photochemistry, particularly visible light photo-processes, have allowed for controllable generation of free radicals as well as the subsequent bond formations. The past five years have witnessed dramatic advances in exploring photo-induced catalytic asymmetric free radical reactions, and enormous potentials along this line are envisaged. This perspective gives a brief summary on the important advances in this field. Accordingly, the major advances are classified based on different radical species including alpha-amino/oxyl radicals, radicals generated from enones and its analogues, benzyl radicals, alpha-carbonyl radicals, polyhalogenated alkyl radicals and nitrogen radicals. Brief discussion of mechanism is presented whenever relevant. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38158]  |
| 专题 | 化学研究所_分子识别与功能实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Mol Recognit & Funct, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang Dehong,Zhang Long,Luo Sanzhong. Photo-induced Catalytic Asymmetric Free Radical Reactions[J]. ACTA CHIMICA SINICA,2017,75(1):22-33. |
| APA | Wang Dehong,Zhang Long,&Luo Sanzhong.(2017).Photo-induced Catalytic Asymmetric Free Radical Reactions.ACTA CHIMICA SINICA,75(1),22-33. |
| MLA | Wang Dehong,et al."Photo-induced Catalytic Asymmetric Free Radical Reactions".ACTA CHIMICA SINICA 75.1(2017):22-33. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。