Efficient Conjugated Polymer-Methyl Viologen Electron Transfer System for Controlled Photo-Driven Hydrogen Evolution
文献类型：期刊论文
| 作者 | Lu, Huan1; Hu, Rong1; Bai, Haotian1; Chen, Hui1; Lv, Fengting1; Liu, Libing1; Wang, Shu1; Tian, He2 |
| 刊名 | ACS APPLIED MATERIALS & INTERFACES
 |
| 出版日期 | 2017-03-29 |
| 卷号 | 9期号:12页码:10355-10359 |
| 关键词 | Hydrogen Generation Conjugated Polymeri Light Catalysis Self-assembly Switch |
| 英文摘要 | Photodriven hydrogen production has been a good strategy in solar energy utilization. In this work, we use a water-soluble negatively charged polythiophene derivative as photosensitizer to produce hydrogen from aqueous solution containing methyl viologen (MV2+), ethylenediaminetetraacetic acid disodium salt (EDTA), and a colloidal platinum catalyst upon exposure to xenon lamp (>420 nm) or natural sunlight. The supramolecular assembly and dis-assembly processes of MV2+ and cucurbit[8]uril (CB[8]) was further used to reversibly "turn-on" and "turn-off" hydrogen generation of the polymer system. This research offers a proof-of-concept to control hydrogen generation in demand, which is an advantage for hydrogen utilization and storage. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38211]  |
| 专题 | 化学研究所_有机固体实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Organ Solids, Beijing 100190, Peoples R China 2.East China Univ Sci & Technol, Coll Chem & Mol Engn, Shanghai 200237, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lu, Huan,Hu, Rong,Bai, Haotian,et al. Efficient Conjugated Polymer-Methyl Viologen Electron Transfer System for Controlled Photo-Driven Hydrogen Evolution[J]. ACS APPLIED MATERIALS & INTERFACES,2017,9(12):10355-10359. |
| APA | Lu, Huan.,Hu, Rong.,Bai, Haotian.,Chen, Hui.,Lv, Fengting.,...&Tian, He.(2017).Efficient Conjugated Polymer-Methyl Viologen Electron Transfer System for Controlled Photo-Driven Hydrogen Evolution.ACS APPLIED MATERIALS & INTERFACES,9(12),10355-10359. |
| MLA | Lu, Huan,et al."Efficient Conjugated Polymer-Methyl Viologen Electron Transfer System for Controlled Photo-Driven Hydrogen Evolution".ACS APPLIED MATERIALS & INTERFACES 9.12(2017):10355-10359. |
入库方式： OAI收割
来源：化学研究所
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