Enantioselective Terminal Addition to Allenes by Dual Chiral Primary Amine/Palladium Catalysis
文献类型：期刊论文
| 作者 | Zhou, Han; Wang, Yaning; Zhang, Long; Cai, Mao; Luo, Sanzhong1 |
| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
 |
| 出版日期 | 2017-03-15 |
| 卷号 | 139期号:10页码:3631-3634 |
| 英文摘要 | We herein describe a synergistic chiral primary amine/achiral palladium catalyzed enantioselective terminal addition to allenes with alpha-branched,beta-ketocarbonyls and aldehydes. The reactions afford allylic adducts bearing acyclic all-carbon quaternary centers with high regio- and enantioselectivity. A wide range of allenes including those aliphatic or 1,1'-disubstituted could be employed, thus expanding the scope of typical asymmetric allylic alkylation reactions. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38214]  |
| 专题 | 化学研究所_分子识别与功能实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Mol Recognit & Funct, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Dept Chem, Beijing 100049, Peoples R China 3.Collaborat Innovat Ctr Chem Sci & Engn, Tianjin 300071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Han,Wang, Yaning,Zhang, Long,et al. Enantioselective Terminal Addition to Allenes by Dual Chiral Primary Amine/Palladium Catalysis[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2017,139(10):3631-3634. |
| APA | Zhou, Han,Wang, Yaning,Zhang, Long,Cai, Mao,&Luo, Sanzhong.(2017).Enantioselective Terminal Addition to Allenes by Dual Chiral Primary Amine/Palladium Catalysis.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,139(10),3631-3634. |
| MLA | Zhou, Han,et al."Enantioselective Terminal Addition to Allenes by Dual Chiral Primary Amine/Palladium Catalysis".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 139.10(2017):3631-3634. |
入库方式： OAI收割
来源：化学研究所
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