中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Ultra Water Repellent Polypropylene Surfaces with Tunable Water Adhesion

文献类型:期刊论文

作者Zhu, Tang1,2; Cai, Chao1,2; Guo, Jing1,2; Wang, Rong1,2; Zhao, Ning1; Xu, Jian1
刊名ACS APPLIED MATERIALS & INTERFACES
出版日期2017-03-22
卷号9期号:11页码:10224-10232
关键词Adhesion Crystallization Microstructure Polypropylene Water Repellent
英文摘要Polypropylene (PP), including isotactic PP (i-PP) and atactic PP (a-PP) with distinct tacticity, is one of the most widely used general plastics. Herein, ultra water repellent PP coatings with tunable adhesion to water were prepared via a simple casting method. The pure i-PP coating shows a hierarchical morphology with micro/nanobinary structures, exhibiting a water contact angle (CA) larger than 150 degrees and a sliding angle less than 5 degrees (for 5 mu L water droplet). In contrast, the pure a-PP coating has a less rough morphology with a water contact angle of about 130 degrees, and the water droplets stick on the coating at any tilted angles. For the composite i-PP/a-PP coatings, however, ultra water repellency with CA > 150 degrees but water adhesion tailorable from slippery to sticky can be realized, depending on the contents of a-PP and i-PP. The different wetting behaviors are due to the various microstructures of the composite coatings resulting from the distinct crystallization ability of a-PP and i-PP. Furthermore, the existence of a-PP in the composite coatings enhances the mechanical properties compared to the i-PP coating. The proposed method is feasible to modify various substrates and potential applications in no-loss liquid transportation, slippery surfaces, and patterned superhydrophobic surfaces are demonstrated.
语种英语
源URL[http://ir.iccas.ac.cn/handle/121111/38218]  
专题化学研究所_高分子物理与化学实验室
作者单位1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Lab Polymer Phys & Chem, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Zhu, Tang,Cai, Chao,Guo, Jing,et al. Ultra Water Repellent Polypropylene Surfaces with Tunable Water Adhesion[J]. ACS APPLIED MATERIALS & INTERFACES,2017,9(11):10224-10232.
APA Zhu, Tang,Cai, Chao,Guo, Jing,Wang, Rong,Zhao, Ning,&Xu, Jian.(2017).Ultra Water Repellent Polypropylene Surfaces with Tunable Water Adhesion.ACS APPLIED MATERIALS & INTERFACES,9(11),10224-10232.
MLA Zhu, Tang,et al."Ultra Water Repellent Polypropylene Surfaces with Tunable Water Adhesion".ACS APPLIED MATERIALS & INTERFACES 9.11(2017):10224-10232.

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来源:化学研究所

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