Ultra Water Repellent Polypropylene Surfaces with Tunable Water Adhesion
文献类型:期刊论文
作者 | Zhu, Tang1,2; Cai, Chao1,2; Guo, Jing1,2; Wang, Rong1,2; Zhao, Ning1; Xu, Jian1 |
刊名 | ACS APPLIED MATERIALS & INTERFACES |
出版日期 | 2017-03-22 |
卷号 | 9期号:11页码:10224-10232 |
关键词 | Adhesion Crystallization Microstructure Polypropylene Water Repellent |
英文摘要 | Polypropylene (PP), including isotactic PP (i-PP) and atactic PP (a-PP) with distinct tacticity, is one of the most widely used general plastics. Herein, ultra water repellent PP coatings with tunable adhesion to water were prepared via a simple casting method. The pure i-PP coating shows a hierarchical morphology with micro/nanobinary structures, exhibiting a water contact angle (CA) larger than 150 degrees and a sliding angle less than 5 degrees (for 5 mu L water droplet). In contrast, the pure a-PP coating has a less rough morphology with a water contact angle of about 130 degrees, and the water droplets stick on the coating at any tilted angles. For the composite i-PP/a-PP coatings, however, ultra water repellency with CA > 150 degrees but water adhesion tailorable from slippery to sticky can be realized, depending on the contents of a-PP and i-PP. The different wetting behaviors are due to the various microstructures of the composite coatings resulting from the distinct crystallization ability of a-PP and i-PP. Furthermore, the existence of a-PP in the composite coatings enhances the mechanical properties compared to the i-PP coating. The proposed method is feasible to modify various substrates and potential applications in no-loss liquid transportation, slippery surfaces, and patterned superhydrophobic surfaces are demonstrated. |
语种 | 英语 |
源URL | [http://ir.iccas.ac.cn/handle/121111/38218] |
专题 | 化学研究所_高分子物理与化学实验室 |
作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Lab Polymer Phys & Chem, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zhu, Tang,Cai, Chao,Guo, Jing,et al. Ultra Water Repellent Polypropylene Surfaces with Tunable Water Adhesion[J]. ACS APPLIED MATERIALS & INTERFACES,2017,9(11):10224-10232. |
APA | Zhu, Tang,Cai, Chao,Guo, Jing,Wang, Rong,Zhao, Ning,&Xu, Jian.(2017).Ultra Water Repellent Polypropylene Surfaces with Tunable Water Adhesion.ACS APPLIED MATERIALS & INTERFACES,9(11),10224-10232. |
MLA | Zhu, Tang,et al."Ultra Water Repellent Polypropylene Surfaces with Tunable Water Adhesion".ACS APPLIED MATERIALS & INTERFACES 9.11(2017):10224-10232. |
入库方式: OAI收割
来源:化学研究所
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