Synthesis of Asymmetrical Organic Carbonates using CO2 as a Feedstock in AgCl/Ionic Liquid System at Ambient Conditions
文献类型：期刊论文
| 作者 | Hu, Jiayin1,2,3; Ma, Jun1,2; Lu, Lu1,2,3; Qian, Qingli1,2; Zhang, Zhaofu1,2; Xie, Chao1,2,3; Han, Buxing1,2,3 |
| 刊名 | CHEMSUSCHEM
 |
| 出版日期 | 2017-03-22 |
| 卷号 | 10期号:6页码:1292-1297 |
| 关键词 | Asymmetrical Carbonates Carbon Dioxide Fixation Ionic Liquids Propargylic Alcohols |
| 英文摘要 | Synthesis of asymmetrical organic carbonates from the renewable and inexpensive CO2 is of great importance but also challenging, especially at ambient conditions. Herein, we found that some metal salt/ionic liquid catalyst systems were highly active for the synthesis of asymmetrical organic carbonates from CO2, propargylic alcohols, and primary alcohols. Especially, the AgCl/1-butyl-3-methylimidazolium acetate ([Bmim][OAc]) system was very efficient for the reactions of a wide range of substrates at room temperature and atmospheric pressure, and the yields of the asymmetrical organic carbonates could approach 100%. The catalyst system could be reused at least five times without changing its catalytic performance, and could be easily recovered and reused. A detailed study indicated that AgCl and [Bmim][OAc] catalyzed the reactions cooperatively, resulting in unique catalytic performance. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38231]  |
| 专题 | 化学研究所_胶体、界面与化学热力学实验室 |
| 作者单位 | 1.Chinese Acad Sci, BNLMS, CAS Key Lab Colloid & Interface, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Thermodynam Inst Chem, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hu, Jiayin,Ma, Jun,Lu, Lu,et al. Synthesis of Asymmetrical Organic Carbonates using CO2 as a Feedstock in AgCl/Ionic Liquid System at Ambient Conditions[J]. CHEMSUSCHEM,2017,10(6):1292-1297. |
| APA | Hu, Jiayin.,Ma, Jun.,Lu, Lu.,Qian, Qingli.,Zhang, Zhaofu.,...&Han, Buxing.(2017).Synthesis of Asymmetrical Organic Carbonates using CO2 as a Feedstock in AgCl/Ionic Liquid System at Ambient Conditions.CHEMSUSCHEM,10(6),1292-1297. |
| MLA | Hu, Jiayin,et al."Synthesis of Asymmetrical Organic Carbonates using CO2 as a Feedstock in AgCl/Ionic Liquid System at Ambient Conditions".CHEMSUSCHEM 10.6(2017):1292-1297. |
入库方式： OAI收割
来源：化学研究所
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