Efficient and Robust Reactions for Polyethylene Covalently Grafted Carbon Nanotubes
文献类型：期刊论文
| 作者 | Zhang, Yongjie1,2; Li, Qian1; Wang, Wenbo2; Guo, Anru3; Li, Jie3; Li, Huayi1 |
| 刊名 | MACROMOLECULAR CHEMISTRY AND PHYSICS
 |
| 出版日期 | 2017-02-01 |
| 卷号 | 218期号:4 |
| 关键词 | Hydrolytic Condensation Nanocomposite Polyethylene Grafted Mwnt Thiol-ene Addition |
| 英文摘要 | Surface modification of carbon nanotubes (CNTs) with long polymer chains has attracted great attention since it promises high performance nanomaterials. However, due to the chemical inertness of both polyethylene (PE) and CNT, it still remains a challenge to covalently conjugate CNT with PE in a facile manner. In this report, trimethoxysilane terminated PE (TMS-PE) and trimethoxysilane modified multiwall carbon nanotube (TMS-MWNT) is prepared through radical mediated thiol-ene addition reaction between (3-mercaptopropyl) trimethoxysilane and vinyl terminated PE or pristine carbon nanotube, respectively. Subsequently, organotin-catalyzed hydrolytic co-condensation of TMS-PE and TMS-MWNT lead to PE covalently grafted mutliwall CNT (PE-Si-MWNT) with high graft ratio (17.5 wt%). Such reactions are robust and efficient and the reaction conditions are mild. In addition, the authors provide the very first evidence that end-grafted PE chains in PE-Si-MWNT, which are clearly observed in TEM images, can render high compatibility and good interfacial interactions between CNT and low density PE (LDPE) matrix and thus promote homogeneous dispersion of CNT into LDPE matrix as shown by scanning electron microscopy (SEM) characterization of brittle fracture surfaces of LDPE/PE-Si-MWNT nanocomposites. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38235]  |
| 专题 | 化学研究所_工程塑料实验室 |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, CAS Key Lab Engn Plast, Beijing 100190, Peoples R China 2.Dalian Polytechn Univ, Sch Text & Mat Engn, Dalian 116034, Peoples R China 3.Aerosp Res Inst Mat & Proc Technol, Beijing 100076, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Yongjie,Li, Qian,Wang, Wenbo,et al. Efficient and Robust Reactions for Polyethylene Covalently Grafted Carbon Nanotubes[J]. MACROMOLECULAR CHEMISTRY AND PHYSICS,2017,218(4). |
| APA | Zhang, Yongjie,Li, Qian,Wang, Wenbo,Guo, Anru,Li, Jie,&Li, Huayi.(2017).Efficient and Robust Reactions for Polyethylene Covalently Grafted Carbon Nanotubes.MACROMOLECULAR CHEMISTRY AND PHYSICS,218(4). |
| MLA | Zhang, Yongjie,et al."Efficient and Robust Reactions for Polyethylene Covalently Grafted Carbon Nanotubes".MACROMOLECULAR CHEMISTRY AND PHYSICS 218.4(2017). |
入库方式： OAI收割
来源：化学研究所
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