Jones oxidation of glycerol catalysed by small gold clusters
文献类型：期刊论文
| 作者 | Pembere, Anthony M.; Luo, Zhixun |
| 刊名 | PHYSICAL CHEMISTRY CHEMICAL PHYSICS
 |
| 出版日期 | 2017-03-07 |
| 卷号 | 19期号:9页码:6620-6625 |
| 英文摘要 | We present here a joint theoretical and experimental study on the oxidation reactivity of glycerol catalysed by chemically pure small Au clusters in the absence and presence of H2O2. From highresolution mass spectrometry, fruitful products of glyceraldehyde, glyceric acid, tartronic acid, mesoxalic acid and glycolic acid are observed pertaining to the successive Jones oxidation process associated with C-O and C-H bond activation. We then fully demonstrate the reaction pathways on the basis of a complementary-active-sites mechanism, revealing the favourable dehydration of glycerol followed by oxidation to form glyceraldehyde and carboxylic acids in the presence of small Au clusters and H2O2. It is found that the Au-n/H2O2 system undertakes a heterolytic mechanism by firstly transferring an O-atom from H2O2 to the Au cluster forming an active intermediate, on which hydride abstraction and subsequent oxygen rebound become thermodynamically possible, promoting the C-H insertion reaction and further oxidation of aldehyde to carboxylic acids. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38242]  |
| 专题 | 化学研究所_分子动态与稳态结构实验室 |
| 作者单位 | Chinese Acad Sci, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Pembere, Anthony M.,Luo, Zhixun. Jones oxidation of glycerol catalysed by small gold clusters[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2017,19(9):6620-6625. |
| APA | Pembere, Anthony M.,&Luo, Zhixun.(2017).Jones oxidation of glycerol catalysed by small gold clusters.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,19(9),6620-6625. |
| MLA | Pembere, Anthony M.,et al."Jones oxidation of glycerol catalysed by small gold clusters".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 19.9(2017):6620-6625. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。