Formation of Gas-Phase Formate in Thermal Reactions of Carbon Dioxide with Diatomic Iron Hydride Anions
文献类型：期刊论文
| 作者 | Jiang, Li-Xue1,3; Zhao, Chongyang2,3; Li, Xiao-Na1; Chen, Hui2; He, Sheng-Gui1 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2017-04-03 |
| 卷号 | 56期号:15页码:4187-4191 |
| 关键词 | Carbon Dioxide Hydrogenation Iron Hydride Mass Spectrometry Quantum-chemical Calculations |
| 英文摘要 | The hydrogenation of carbon dioxide involves the activation of the thermodynamically very stable molecule CO2 and formation of a C-H bond. Herein, we report that HCO2- and CO can be formed in the thermal reaction of CO2 with a diatomic metal hydride species, FeH-. The FeH- anions were produced by laser ablation, and the reaction with CO2 was analyzed by mass spectrometry and quantum-chemical calculations. Gas-phase HCO2- was observed directly as a product, and its formation was predicted to proceed by facile hydride transfer. The mechanism of CO2 hydrogenation in this gas-phase study parallels similar behavior of a condensed-phase iron catalyst. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38267]  |
| 专题 | 化学研究所_分子动态与稳态结构实验室 |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Chem, Key Lab Photochem, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang, Li-Xue,Zhao, Chongyang,Li, Xiao-Na,et al. Formation of Gas-Phase Formate in Thermal Reactions of Carbon Dioxide with Diatomic Iron Hydride Anions[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017,56(15):4187-4191. |
| APA | Jiang, Li-Xue,Zhao, Chongyang,Li, Xiao-Na,Chen, Hui,&He, Sheng-Gui.(2017).Formation of Gas-Phase Formate in Thermal Reactions of Carbon Dioxide with Diatomic Iron Hydride Anions.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,56(15),4187-4191. |
| MLA | Jiang, Li-Xue,et al."Formation of Gas-Phase Formate in Thermal Reactions of Carbon Dioxide with Diatomic Iron Hydride Anions".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56.15(2017):4187-4191. |
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来源：化学研究所
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