中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Low temperature, atmospheric pressure for synthesis of a new carbon Eneyne and application in Li storage

文献类型:期刊论文

作者Jia, Zhiyu1; Zuo, Zicheng1; Yi, Yuanping1; Liu, Huibiao1,3; Li, Dan2; Li, Yongjun1,3; Li, Yuliang1,3
刊名NANO ENERGY
出版日期2017-03-01
卷号33页码:343-349
关键词Carbon Ene-yne Solvent-phase Alkadiyne Conductivity Li Storage
英文摘要Carbon Ene-yne (CEY), a novel two-dimensional full carbon material, was synthesized from tetraethynylethene. Compared with the traditional preparation method of carbon materials, CEY was synthesized by chemical method in solvent-phase under mild condition (low temperature, atmospheric pressure). Diyne of CEY were connected through vinyl groups which is help for pi-electron transition, thus this new material exhibits excellent electronic property. Small band gap of 0.05 eV was predicted for CEY, and high conductivity of CEY film is up to 1.4x10(-2) S/m which facilitates its application in electronic devices. Lithium-ion batteries featuring CEY-based electrode exhibit excellent electrochemical performance, including high specific capacities, outstanding rate performances, and a long cycle lives. We obtained a much high and reversible capacities of up to 410 mA h/g even after a long-term cycling at a high current density of 748 mA/g. Additionally, prepared by our mild solvent-phase chemical method, CEY might be a new star as a versatile materials for many electrochemical applications.
语种英语
源URL[http://ir.iccas.ac.cn/handle/121111/38275]  
专题化学研究所_有机固体实验室
作者单位1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Organ Solids, Beijing 100190, Peoples R China
2.Shantou Univ, Dept Chem, Shantou 515063, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Jia, Zhiyu,Zuo, Zicheng,Yi, Yuanping,et al. Low temperature, atmospheric pressure for synthesis of a new carbon Eneyne and application in Li storage[J]. NANO ENERGY,2017,33:343-349.
APA Jia, Zhiyu.,Zuo, Zicheng.,Yi, Yuanping.,Liu, Huibiao.,Li, Dan.,...&Li, Yuliang.(2017).Low temperature, atmospheric pressure for synthesis of a new carbon Eneyne and application in Li storage.NANO ENERGY,33,343-349.
MLA Jia, Zhiyu,et al."Low temperature, atmospheric pressure for synthesis of a new carbon Eneyne and application in Li storage".NANO ENERGY 33(2017):343-349.

入库方式: OAI收割

来源:化学研究所

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