Design, Synthesis, and Photovoltaic Characterization of a Small Molecular Acceptor with an Ultra-Narrow Band Gap
文献类型：期刊论文
| 作者 | Yao, Huifeng1,2; Cui, Yong1,2; Yu, Runnan1,2; Gao, Bowei1,2; Zhang, Hao1,2; Hou, Jianhui1,2 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2017-03-06 |
| 卷号 | 56期号:11页码:3045-3049 |
| 关键词 | Fluorination Intramolecular Charge Transfer Non-fullerene Acceptors Organic Solar Cells Ultra-narrow Band Gap |
| 英文摘要 | The design of narrow band gap (NBG) donors or acceptors and their application in organic solar cells (OSCs) are of great importance in the conversion of solar photons to electrons. Limited by the inevitable energy loss from the optical band gap of the photovoltaic material to the open-circuit voltage of the OSC device, the improvement of the power conversion efficiency (PCE) of NBG-based OSCs faces great challenges. A novel acceptor-donor-acceptor structured non-fullerene acceptor is reported with an ultra-narrow band gap of 1.24 eV, which was achieved by an enhanced intramolecular charge transfer (ICT) effect. In the OSC device, despite a low energy loss of 0.509 eV, an impressive short-circuit current density of 25.3 mA cm(-2) is still recorded, which is the highest value for all OSC devices. The high 10.9% PCE of the NBG-based OSC demonstrates that the design and application of ultra-narrow materials have the potential to further improve the PCE of OSC devices. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38279]  |
| 专题 | 化学研究所_高分子物理与化学实验室 |
| 作者单位 | 1.Chinese Acad Sci, State Key Lab Polymer Phys & Chem, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yao, Huifeng,Cui, Yong,Yu, Runnan,et al. Design, Synthesis, and Photovoltaic Characterization of a Small Molecular Acceptor with an Ultra-Narrow Band Gap[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017,56(11):3045-3049. |
| APA | Yao, Huifeng,Cui, Yong,Yu, Runnan,Gao, Bowei,Zhang, Hao,&Hou, Jianhui.(2017).Design, Synthesis, and Photovoltaic Characterization of a Small Molecular Acceptor with an Ultra-Narrow Band Gap.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,56(11),3045-3049. |
| MLA | Yao, Huifeng,et al."Design, Synthesis, and Photovoltaic Characterization of a Small Molecular Acceptor with an Ultra-Narrow Band Gap".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56.11(2017):3045-3049. |
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来源：化学研究所
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