In situ growth of gold nanoparticles on hydrogen-bond supramolecular structures with high peroxidase-like activity at neutral pH and their application to one-pot blood glucose sensing
文献类型：期刊论文
| 作者 | Li, Ruimin1; Zhou, Yue2; Zou, Li1; Li, Shumu2; Wang, Jing1; Shu, Chunying2; Wang, Chunru2; Ge, Jiechao3; Ling, Liansheng1 |
| 刊名 | SENSORS AND ACTUATORS B-CHEMICAL
 |
| 出版日期 | 2017-06-01 |
| 卷号 | 245页码:656-664 |
| 关键词 | Hydrogen-bond Supramolecular Structures Gold Nanoparticles Peroxidase-like Neutral Ph Blood Glucose |
| 英文摘要 | A simple and general procedure is designed for in situ growth of gold nanoparticles (AuNPs) on hydrogen bond supramolecular structures. The resulting nanocomposites are obtained via a one-pot synthetic method using chloroauric acid (HAuCl4), sodium citrate, melamine (M) and cyanuric acid (CA) as precursors. At room temperature, melamine cyanurate (MCA) is formed immediately by M and CA through hydrogen bond self-assembly, possesses rich nitrogen content (49.4 wt%), and provides evenly dispersed and active sites to anchor and stabilize gold nanoparticles (AuNPs) as an ideal scaffold. The nanocomposites (AuNPs/MCA) exhibit high peroxidase-like activity that can catalyze the oxidation-reduction reaction of H2O2 and peroxidase substrates over a broad pH range, including nearly neutral conditions (pH 5.0-7.4), as well as excellent stability. Combined with glucose oxidase (GO(x), AuNPs/MCA are successfully used for the quantitative determination of blood glucose via one-pot colorimetric assay. This study develops an economic approach for preparation of peroxidase mimetics with high catalytic activity at neutral pH, and well stability, expected to provide guidelines for other types of inorganic/supramolecule nanocomposites, and to broaden their applications in analytical chemistry and environmental science. (C) 2017 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38336]  |
| 专题 | 化学研究所_分子纳米结构与纳米技术实验室 |
| 作者单位 | 1.Sun Yat Sen Univ, Sch Chem, Guangzhou 510275, Guangdong, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Key Lab Mol Nanostruct & Nanotechnol, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Ruimin,Zhou, Yue,Zou, Li,et al. In situ growth of gold nanoparticles on hydrogen-bond supramolecular structures with high peroxidase-like activity at neutral pH and their application to one-pot blood glucose sensing[J]. SENSORS AND ACTUATORS B-CHEMICAL,2017,245:656-664. |
| APA | Li, Ruimin.,Zhou, Yue.,Zou, Li.,Li, Shumu.,Wang, Jing.,...&Ling, Liansheng.(2017).In situ growth of gold nanoparticles on hydrogen-bond supramolecular structures with high peroxidase-like activity at neutral pH and their application to one-pot blood glucose sensing.SENSORS AND ACTUATORS B-CHEMICAL,245,656-664. |
| MLA | Li, Ruimin,et al."In situ growth of gold nanoparticles on hydrogen-bond supramolecular structures with high peroxidase-like activity at neutral pH and their application to one-pot blood glucose sensing".SENSORS AND ACTUATORS B-CHEMICAL 245(2017):656-664. |
入库方式： OAI收割
来源：化学研究所
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