Controlled ring-opening polymerization of alpha-amino acid N-carboxy-anhydride by frustrated amine/borane Lewis pairs
文献类型:期刊论文
作者 | Zhang, Hongyuan1; Nie, Yanzhao1; Zhi, Xinmei1; Du, Haifeng2; Yang, Jing1 |
刊名 | CHEMICAL COMMUNICATIONS
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出版日期 | 2017-05-07 |
卷号 | 53期号:37页码:5155-5158 |
英文摘要 | In this communication, we presented a novel strategy to control the ROP of alpha-amino acid N-carboxy-anhydrides using the concept of frustrated Lewis pairs (FLPs). An FLP intermediate containing an interaction between the bulky borane Lewis acid and the amine groups of the propagation chain end is essential to accomplish the polypeptide synthesis with well-defined structures under mild conditions. |
语种 | 英语 |
源URL | [http://ir.iccas.ac.cn/handle/121111/38389] ![]() |
专题 | 化学研究所_分子识别与功能实验室 |
作者单位 | 1.Beijing Univ Chem Technol, Coll Life Sci & Technol, Beijing Key Lab Bioproc, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China 2.Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Hongyuan,Nie, Yanzhao,Zhi, Xinmei,et al. Controlled ring-opening polymerization of alpha-amino acid N-carboxy-anhydride by frustrated amine/borane Lewis pairs[J]. CHEMICAL COMMUNICATIONS,2017,53(37):5155-5158. |
APA | Zhang, Hongyuan,Nie, Yanzhao,Zhi, Xinmei,Du, Haifeng,&Yang, Jing.(2017).Controlled ring-opening polymerization of alpha-amino acid N-carboxy-anhydride by frustrated amine/borane Lewis pairs.CHEMICAL COMMUNICATIONS,53(37),5155-5158. |
MLA | Zhang, Hongyuan,et al."Controlled ring-opening polymerization of alpha-amino acid N-carboxy-anhydride by frustrated amine/borane Lewis pairs".CHEMICAL COMMUNICATIONS 53.37(2017):5155-5158. |
入库方式: OAI收割
来源:化学研究所
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