Pyridinium-Substituted TetraphenylethyleneEntailing Alkyne Moiety: Enhancement of Photosensitizing Efficiency and Antimicrobial Activity
文献类型：期刊论文
| 作者 | You, Xue1,2; Ma, Huili3; Wang, Yuancheng1,2; Zhang, Guanxin1; Peng, Qian1; Liu, Libing1; Wang, Shu1,2; Zhang, Deqing1,2 |
| 刊名 | CHEMISTRY-AN ASIAN JOURNAL
 |
| 出版日期 | 2017-05-04 |
| 卷号 | 12期号:9页码:1013-1019 |
| 关键词 | Aggregation-induced Emission Fluorescent Probes Photodynamic Therapy Singlet Oxygen Tetraphenylethylene |
| 英文摘要 | Apart from sensing and imaging, luminogens with aggregation-induced emission (AIE) are also interesting for photosensitizing. The photosensitizing behavior and bacteria-killing performance of a pyridinium-substituted tetraphenylethylene with an alkyne group (TPE-A-Py+) is reported herein. Interestingly, TPE-A-Py+ exhibits higher photosensitizing efficiency than TPE-Py+ (without alkyne group) when I- was used as a counteranion. This is well explained by the fact that the (ST) between the excited singlet state (S-1) and triplet state (T-1) was lower for TPE-A-Py+ than for TPE-Py+, according to theoretical calculations. Moreover, replacement of I- with other anions (PF6-, N(SO2CF3)(2)(-) and BPh4-) led to a decrease of photosensitizing efficiency for TPE-A-Py+. Notably, TPE-A-Py+ could be used as an efficient photosensitizer to photo-inactivate ampicillin-resistant (amp(r)) E.coli at low concentration under white-light irradiation very quickly. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38420]  |
| 专题 | 化学研究所_有机固体实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, CAS Key Lab Organ Solids, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Tsinghua Univ, Dept Chem, Key Lab Organ OptoElect & Mol Engn, Beijing 100084, Peoples R China |
| 推荐引用方式 GB/T 7714 | You, Xue,Ma, Huili,Wang, Yuancheng,et al. Pyridinium-Substituted TetraphenylethyleneEntailing Alkyne Moiety: Enhancement of Photosensitizing Efficiency and Antimicrobial Activity[J]. CHEMISTRY-AN ASIAN JOURNAL,2017,12(9):1013-1019. |
| APA | You, Xue.,Ma, Huili.,Wang, Yuancheng.,Zhang, Guanxin.,Peng, Qian.,...&Zhang, Deqing.(2017).Pyridinium-Substituted TetraphenylethyleneEntailing Alkyne Moiety: Enhancement of Photosensitizing Efficiency and Antimicrobial Activity.CHEMISTRY-AN ASIAN JOURNAL,12(9),1013-1019. |
| MLA | You, Xue,et al."Pyridinium-Substituted TetraphenylethyleneEntailing Alkyne Moiety: Enhancement of Photosensitizing Efficiency and Antimicrobial Activity".CHEMISTRY-AN ASIAN JOURNAL 12.9(2017):1013-1019. |
入库方式： OAI收割
来源：化学研究所
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