Characterization of organic aerosol in Beijing by laser desorption ionization coupled with Fourier Transform Ion Cyclotron Resonance Mass spectrometry
文献类型：期刊论文
| 作者 | Xue, Jinjuan1,3; Li, Yafeng1,3; Xie, Xiaobo1,3; Xiong, Caiqiao1; Liu, Huihui1; Chen, Suming1; Nie, Zongxiu1,3,4; Chen, Chuncheng2,3; Zhao, Jincai2,3 |
| 刊名 | ATMOSPHERIC ENVIRONMENT
 |
| 出版日期 | 2017-06-01 |
| 卷号 | 159页码:55-65 |
| 关键词 | Organic Aerosol Ldi-ft-icr Pahs Organoamines Mass Spectrometry |
| 英文摘要 | In order to resolve the organic compositions in the atmospheric aerosol which is significant for understanding the formation mechanism of particulate matter and their harm for human health, a direct laser desorption ionization (LDI) coupled with Fourier Transform Resonance Mass (FT-ICR MS) was utilized for characterizing the aerosol particles collected in Beijing during winter. A lot of organic compounds can be detected by direct laser desorption ionization of the aerosol particular with different size collected on aluminum foil without complicated sample pretreatment process. In addition, semi quantification of the organic compounds can be achieved with solvent extraction procedure. It was found that the ubiquitous polycyclic aromatic hydrocarbons (PAHs) contaminants in the aerosol could serve as matrix, which helps the detection of many kinds of compounds including highly saturated amphiphilic long alkyl chain compounds (carbon number > 16), like aliphatic amines in positive ion mode and organosulfates in negative ion mode. Based on the accurate mass measurement results, elemental compositions of over 1500 peaks in the mass spectrum were derived, and we categorized them into five groups according to their elemental compositions in order to provide helpful information for tracing the pollution source. It is demonstrated that abundant information about the organic components in the atmospheric aerosol can be provided by direct LDI FT-ICR MS method, and these information will largely facilitate further studies on origin and formation process of the aerosol. (C) 2017 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38429]  |
| 专题 | 化学研究所_活体分析化学实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Analyt Chem Living Biosyst, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Natl Ctr Mass Spectrometry Beijing, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xue, Jinjuan,Li, Yafeng,Xie, Xiaobo,et al. Characterization of organic aerosol in Beijing by laser desorption ionization coupled with Fourier Transform Ion Cyclotron Resonance Mass spectrometry[J]. ATMOSPHERIC ENVIRONMENT,2017,159:55-65. |
| APA | Xue, Jinjuan.,Li, Yafeng.,Xie, Xiaobo.,Xiong, Caiqiao.,Liu, Huihui.,...&Zhao, Jincai.(2017).Characterization of organic aerosol in Beijing by laser desorption ionization coupled with Fourier Transform Ion Cyclotron Resonance Mass spectrometry.ATMOSPHERIC ENVIRONMENT,159,55-65. |
| MLA | Xue, Jinjuan,et al."Characterization of organic aerosol in Beijing by laser desorption ionization coupled with Fourier Transform Ion Cyclotron Resonance Mass spectrometry".ATMOSPHERIC ENVIRONMENT 159(2017):55-65. |
入库方式： OAI收割
来源：化学研究所
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