Heterogeneous Cobalt-Catalyzed Direct N-Formylation of Isoquinolines with CO2 and H-2
文献类型：期刊论文
| 作者 | He, Zhenhong1; Liu, Hangyu1,2; Liu, Huizhen1,2; Qian, Qingli1; Meng, Qinglei1; Mei, Qingqing1,2; Han, Buxing1,2 |
| 刊名 | CHEMCATCHEM
 |
| 出版日期 | 2017-06-08 |
| 卷号 | 9期号:11页码:1947-1952 |
| 关键词 | Carbon Dioxide Formylation Heterogeneous Catalysis Hydrogenation Isoquinolines |
| 英文摘要 | Isoquinolines (IQs) are an abundant feedstock, and N-formyl-1,2,3,4-tetrahydroisoquinolines (FTHIQs) are valuable fine chemicals and key intermediates. Herein, we report for the first time the Co-0/ZnCl2-catalyzed direct N-formylation of IQs by using CO2 with H-2 to produce FTHIQs. It was discovered that the Co catalyst and ZnCl2 worked synergistically in catalyzing the N-formylation reactions, and moderate to high yields of the desired products could be obtained, depending on the nature of the substrates. The Co-0 catalyst could be reused at least five times without a notable decrease in activity. A possible reaction mechanism is proposed on the basis of control experiments. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38533]  |
| 专题 | 化学研究所_胶体、界面与化学热力学实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, BNLMS, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | He, Zhenhong,Liu, Hangyu,Liu, Huizhen,et al. Heterogeneous Cobalt-Catalyzed Direct N-Formylation of Isoquinolines with CO2 and H-2[J]. CHEMCATCHEM,2017,9(11):1947-1952. |
| APA | He, Zhenhong.,Liu, Hangyu.,Liu, Huizhen.,Qian, Qingli.,Meng, Qinglei.,...&Han, Buxing.(2017).Heterogeneous Cobalt-Catalyzed Direct N-Formylation of Isoquinolines with CO2 and H-2.CHEMCATCHEM,9(11),1947-1952. |
| MLA | He, Zhenhong,et al."Heterogeneous Cobalt-Catalyzed Direct N-Formylation of Isoquinolines with CO2 and H-2".CHEMCATCHEM 9.11(2017):1947-1952. |
入库方式： OAI收割
来源：化学研究所
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