中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Achieving over 10% efficiency in a new acceptor ITTC and its blends with hexafluoroquinoxaline based polymers

文献类型:期刊论文

作者Zhang, Zhenzhen1; Feng, Liuliu1; Xu, Shutao1; Yuan, Jun1; Zhang, Zhi-Guo2; Peng, Hongjian1; Li, Yongfang2; Zou, Yingping1,3
刊名JOURNAL OF MATERIALS CHEMISTRY A
出版日期2017-06-14
卷号5期号:22页码:11286-11293
英文摘要A new small molecule, ITTC, bearing an indacenodithieno[3,2-b]thiophene core and a 2-(6-oxo-5,6-dihydro-4H-cyclopenta[c]thiophen-4-ylidene)malononitrile end group, was designed, synthesized and characterized as a non-fullerene electron acceptor. The ITTC possesses strong and broad light absorption, high and balanced charge mobility and a nanoscale interpenetrating morphology when blended with a recently synthesized hexafluoroquinoxaline based polymer donor-HFQx-T. HFQx-T was obtained from a Stille coupling copolymerization of a 2,6-bis(trimethyltin)-4,8-bis(5-(2-ethylhexyl)thiophene-2-yl)benzo[1,2-b:4,5-b']dithiophene electron donating unit and a hexafluoroquinoxaline based electron accepting unit. The device employing HFQx-T as the donor and ITTC as the acceptor delivered a power conversion efficiency (PCE) of 8.19% without any post-treatment. After thermal annealing, an impressive PCE of 10.4% was obtained. This performance is among the highest PCEs reported for fullerene-free polymer solar cells up to date. This study demonstrates the great potential of ITTC as n-type materials for organic electronics.
语种英语
源URL[http://ir.iccas.ac.cn/handle/121111/38556]  
专题化学研究所_有机固体实验室
作者单位1.Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China
2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China
3.Cent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Zhenzhen,Feng, Liuliu,Xu, Shutao,et al. Achieving over 10% efficiency in a new acceptor ITTC and its blends with hexafluoroquinoxaline based polymers[J]. JOURNAL OF MATERIALS CHEMISTRY A,2017,5(22):11286-11293.
APA Zhang, Zhenzhen.,Feng, Liuliu.,Xu, Shutao.,Yuan, Jun.,Zhang, Zhi-Guo.,...&Zou, Yingping.(2017).Achieving over 10% efficiency in a new acceptor ITTC and its blends with hexafluoroquinoxaline based polymers.JOURNAL OF MATERIALS CHEMISTRY A,5(22),11286-11293.
MLA Zhang, Zhenzhen,et al."Achieving over 10% efficiency in a new acceptor ITTC and its blends with hexafluoroquinoxaline based polymers".JOURNAL OF MATERIALS CHEMISTRY A 5.22(2017):11286-11293.

入库方式: OAI收割

来源:化学研究所

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