Achieving over 10% efficiency in a new acceptor ITTC and its blends with hexafluoroquinoxaline based polymers
文献类型:期刊论文
作者 | Zhang, Zhenzhen1; Feng, Liuliu1; Xu, Shutao1; Yuan, Jun1; Zhang, Zhi-Guo2; Peng, Hongjian1; Li, Yongfang2; Zou, Yingping1,3 |
刊名 | JOURNAL OF MATERIALS CHEMISTRY A
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出版日期 | 2017-06-14 |
卷号 | 5期号:22页码:11286-11293 |
英文摘要 | A new small molecule, ITTC, bearing an indacenodithieno[3,2-b]thiophene core and a 2-(6-oxo-5,6-dihydro-4H-cyclopenta[c]thiophen-4-ylidene)malononitrile end group, was designed, synthesized and characterized as a non-fullerene electron acceptor. The ITTC possesses strong and broad light absorption, high and balanced charge mobility and a nanoscale interpenetrating morphology when blended with a recently synthesized hexafluoroquinoxaline based polymer donor-HFQx-T. HFQx-T was obtained from a Stille coupling copolymerization of a 2,6-bis(trimethyltin)-4,8-bis(5-(2-ethylhexyl)thiophene-2-yl)benzo[1,2-b:4,5-b']dithiophene electron donating unit and a hexafluoroquinoxaline based electron accepting unit. The device employing HFQx-T as the donor and ITTC as the acceptor delivered a power conversion efficiency (PCE) of 8.19% without any post-treatment. After thermal annealing, an impressive PCE of 10.4% was obtained. This performance is among the highest PCEs reported for fullerene-free polymer solar cells up to date. This study demonstrates the great potential of ITTC as n-type materials for organic electronics. |
语种 | 英语 |
源URL | [http://ir.iccas.ac.cn/handle/121111/38556] ![]() |
专题 | 化学研究所_有机固体实验室 |
作者单位 | 1.Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China 3.Cent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Zhenzhen,Feng, Liuliu,Xu, Shutao,et al. Achieving over 10% efficiency in a new acceptor ITTC and its blends with hexafluoroquinoxaline based polymers[J]. JOURNAL OF MATERIALS CHEMISTRY A,2017,5(22):11286-11293. |
APA | Zhang, Zhenzhen.,Feng, Liuliu.,Xu, Shutao.,Yuan, Jun.,Zhang, Zhi-Guo.,...&Zou, Yingping.(2017).Achieving over 10% efficiency in a new acceptor ITTC and its blends with hexafluoroquinoxaline based polymers.JOURNAL OF MATERIALS CHEMISTRY A,5(22),11286-11293. |
MLA | Zhang, Zhenzhen,et al."Achieving over 10% efficiency in a new acceptor ITTC and its blends with hexafluoroquinoxaline based polymers".JOURNAL OF MATERIALS CHEMISTRY A 5.22(2017):11286-11293. |
入库方式: OAI收割
来源:化学研究所
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