Preparation of recyclable polybutadiene rubber based on acid-base complexation
文献类型：期刊论文
| 作者 | Cui, Kejian1,2; Wang, Dong2; Zhang, Huan2; Guo, Jing2; Cai, Chao2; Zhu, Caizhen1; Zhao, Ning2; Xu, Jian2 |
| 刊名 | JOURNAL OF APPLIED POLYMER SCIENCE
 |
| 出版日期 | 2017-09-20 |
| 卷号 | 134期号:36 |
| 关键词 | Acid-base Complexation Ionic Hydrogen Bond Recycling Rubber Thermoreversible |
| 英文摘要 | Thermoreversible polybutadiene (PB) rubber is prepared by the self-assembly of thiol-ene functionalized PB oligomers containing amine and carboxylic acid groups, respectively, via acid-base reaction. The as-formed ionic hydrogen bonds between the amine and carboxylic acid groups function as the crosslinking points to construct the polymer network. By controlling the crosslinking density, a series of materials ranging from soft gel to stiff solid with different physical properties can be obtained. The thermal reversibility of the ionic hydrogen bonds is evidenced by rheometry and temperature-dependent FTIR spectra. In contrast to conventional covalently crosslinked rubbers, the thermoreversible PB rubbers prepared exhibit the capability of thermally reshaping and recycling. (c) 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 134, 45280. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38895]  |
| 专题 | 化学研究所_高分子物理与化学实验室 |
| 作者单位 | 1.Shenzhen Univ, Coll Chem & Chem Engn, Shenzhen 518060, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cui, Kejian,Wang, Dong,Zhang, Huan,et al. Preparation of recyclable polybutadiene rubber based on acid-base complexation[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2017,134(36). |
| APA | Cui, Kejian.,Wang, Dong.,Zhang, Huan.,Guo, Jing.,Cai, Chao.,...&Xu, Jian.(2017).Preparation of recyclable polybutadiene rubber based on acid-base complexation.JOURNAL OF APPLIED POLYMER SCIENCE,134(36). |
| MLA | Cui, Kejian,et al."Preparation of recyclable polybutadiene rubber based on acid-base complexation".JOURNAL OF APPLIED POLYMER SCIENCE 134.36(2017). |
入库方式： OAI收割
来源：化学研究所
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