Enantio- and Diastereoselective Cyclopropanation of beta,gamma-Unsaturated alpha-Ketoester by a Chiral Phosphate/Indium(III) Complex
文献类型：期刊论文
| 作者 | Zhong, Xingren1,2; Lv, Jian1,2,3; Luo, Sanzhong1,2,3 |
| 刊名 | ORGANIC LETTERS
 |
| 出版日期 | 2017-06-16 |
| 卷号 | 19期号:12页码:3331-3334 |
| 英文摘要 | We report herein an enantioselective cyclo-propanation of beta,gamma-unsaturated alpha-ketoesters with diazoesters by the complexes of InBr3 and, Chiral calcitim phosphates The reaction proceeds via a Michael addition-Cyclization pathway to afford highly functionalized chiral Cyclopropanes with excellent enantioselectivities (up to >99% ee) as a single diastereoisomet. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38896]  |
| 专题 | 化学研究所_分子识别与功能实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Mol Recognit & Funct, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Collaborat Innovat Ctr Chem & Engn Tianjin, Tianjin 300071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhong, Xingren,Lv, Jian,Luo, Sanzhong. Enantio- and Diastereoselective Cyclopropanation of beta,gamma-Unsaturated alpha-Ketoester by a Chiral Phosphate/Indium(III) Complex[J]. ORGANIC LETTERS,2017,19(12):3331-3334. |
| APA | Zhong, Xingren,Lv, Jian,&Luo, Sanzhong.(2017).Enantio- and Diastereoselective Cyclopropanation of beta,gamma-Unsaturated alpha-Ketoester by a Chiral Phosphate/Indium(III) Complex.ORGANIC LETTERS,19(12),3331-3334. |
| MLA | Zhong, Xingren,et al."Enantio- and Diastereoselective Cyclopropanation of beta,gamma-Unsaturated alpha-Ketoester by a Chiral Phosphate/Indium(III) Complex".ORGANIC LETTERS 19.12(2017):3331-3334. |
入库方式： OAI收割
来源：化学研究所
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