Reductive Cleavage of C-O Bond in Model Compounds of Lignin
文献类型：期刊论文
| 作者 | Xu, Huanjun; Liu, Xinwei; Zhao, Yanfei; Wu, Cailing; Chen, Yu; Gao, Xiang; Liu, Zhimin |
| 刊名 | CHINESE JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2017-06-01 |
| 卷号 | 35期号:6页码:938-942 |
| 关键词 | Lignin C-o Bond Aryl Ethers Reductive Cleavage Aromatics |
| 英文摘要 | A simple protocol for reductive cleavage of C-O bond in diaryl and aryl methyl ethers was reported, in which NaH served as a reducing agent and (KOBu)-Bu-t as a base and a radical initiator. The combination of NaH and (KOBu)-Bu-t displayed high efficiency for reductive cleavage of C-O bond in diaryl and aryl ethers (e.g., dibenzofuran, diphenyl ether, anisole) without the hydrogenation of the aryl rings, in the absence of any other catalysts or ligands at 140 degrees C, producing corresponding arenes and phenols. It was indicated that the reaction was under a radical mechanism. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38907]  |
| 专题 | 化学研究所_胶体、界面与化学热力学实验室 |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, CAS Key Lab Colloid Interface & Chem Thermodynam, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Huanjun,Liu, Xinwei,Zhao, Yanfei,et al. Reductive Cleavage of C-O Bond in Model Compounds of Lignin[J]. CHINESE JOURNAL OF CHEMISTRY,2017,35(6):938-942. |
| APA | Xu, Huanjun.,Liu, Xinwei.,Zhao, Yanfei.,Wu, Cailing.,Chen, Yu.,...&Liu, Zhimin.(2017).Reductive Cleavage of C-O Bond in Model Compounds of Lignin.CHINESE JOURNAL OF CHEMISTRY,35(6),938-942. |
| MLA | Xu, Huanjun,et al."Reductive Cleavage of C-O Bond in Model Compounds of Lignin".CHINESE JOURNAL OF CHEMISTRY 35.6(2017):938-942. |
入库方式： OAI收割
来源：化学研究所
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