Cooperative effect from cation and anion of pyridine-containing anion-based ionic liquids for catalysing CO2 transformation at ambient conditions
文献类型：期刊论文
| 作者 | Yuan, Guangfeng1,2; Zhao, Yanfei2; Wu, Yunyan2; Li, Ruipeng2; Chen, Yu2; Xu, Dongmei1,2; Liu, Zhimin2 |
| 刊名 | SCIENCE CHINA-CHEMISTRY
 |
| 出版日期 | 2017-07-01 |
| 卷号 | 60期号:7页码:958-963 |
| 关键词 | Ionic Liquids Co2 Transformation Cyclic Carbonates Atmospheric Pressure Room Temperature |
| 英文摘要 | Pyridine-containing anion-based ionic liquids (PA-ILs) with two kinds of interaction sites to bind CO2, e.g., [P-4444][2-OP], were found to be highly efficient for catalysing the cycloaddition reactions of atmospheric CO2 with epoxides at room temperature under metal- and halogen-free conditions, producing a series of cyclic carbonates in high yields. It was demonstrated that the cooperative interaction from two interaction sites in the anions of PA-ILs activated CO2, while the cation activated the epoxides substrates via coordination to the central P+ unit, thus resulting in the high activity of the IL catalysts. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38927]  |
| 专题 | 化学研究所_胶体、界面与化学热力学实验室 |
| 作者单位 | 1.Shandong Univ Sci & Technol, Coll Chem & Environm Engn, Qingdao 266590, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Key Lab Colloid Interface & Thermodynam, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yuan, Guangfeng,Zhao, Yanfei,Wu, Yunyan,et al. Cooperative effect from cation and anion of pyridine-containing anion-based ionic liquids for catalysing CO2 transformation at ambient conditions[J]. SCIENCE CHINA-CHEMISTRY,2017,60(7):958-963. |
| APA | Yuan, Guangfeng.,Zhao, Yanfei.,Wu, Yunyan.,Li, Ruipeng.,Chen, Yu.,...&Liu, Zhimin.(2017).Cooperative effect from cation and anion of pyridine-containing anion-based ionic liquids for catalysing CO2 transformation at ambient conditions.SCIENCE CHINA-CHEMISTRY,60(7),958-963. |
| MLA | Yuan, Guangfeng,et al."Cooperative effect from cation and anion of pyridine-containing anion-based ionic liquids for catalysing CO2 transformation at ambient conditions".SCIENCE CHINA-CHEMISTRY 60.7(2017):958-963. |
入库方式： OAI收割
来源：化学研究所
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