中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Fabrication of multi-stimuli responsive supramolecular hydrogels based on host-guest inclusion complexation of a tadpole-shaped cyclodextrin derivative with the azobenzene dimer

文献类型:期刊论文

作者Wang, Xing1; Wang, Juan1; Yang, Yanyu1,2; Yang, Fei1,2; Wu, Decheng1,2
刊名POLYMER CHEMISTRY
出版日期2017-07-14
卷号8期号:26页码:3901-3909
英文摘要Motivated by the demand for high-performance soft materials for applications in catalysis, drug delivery and biomedical materials, the development of smart hydrogels that possess both biocompatibility and stimulus responsiveness has been highly desirable. Here, we demonstrated a facile method to construct a multi-responsive supramolecular hydrogel by the formation of host-guest complexes between the tadpole-shaped PEG-POSS-(CD)(7) polymer and Azo-SS-Azo dimer. Incorporation of rigid POSS units furnished supramolecular cross-linked networks with high mechanical strength. The reversible gel-sol phase transition of supramolecular hydrogels could be induced by temperature, light and redox while the Azo derivatives could induce a quick gel-sol transition. These novel supramolecular hydrogels also possessed a favorable self-healing ability and better biocompatibility, which endowed the smart hydrogels with potential practical and real-life applications that will be beneficial for further development of more intelligent materials with desired functionalities.
语种英语
源URL[http://ir.iccas.ac.cn/handle/121111/38936]  
专题化学研究所_高分子物理与化学实验室
作者单位1.Chinese Acad Sci, State Key Lab Polymer Phys & Chem, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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GB/T 7714
Wang, Xing,Wang, Juan,Yang, Yanyu,et al. Fabrication of multi-stimuli responsive supramolecular hydrogels based on host-guest inclusion complexation of a tadpole-shaped cyclodextrin derivative with the azobenzene dimer[J]. POLYMER CHEMISTRY,2017,8(26):3901-3909.
APA Wang, Xing,Wang, Juan,Yang, Yanyu,Yang, Fei,&Wu, Decheng.(2017).Fabrication of multi-stimuli responsive supramolecular hydrogels based on host-guest inclusion complexation of a tadpole-shaped cyclodextrin derivative with the azobenzene dimer.POLYMER CHEMISTRY,8(26),3901-3909.
MLA Wang, Xing,et al."Fabrication of multi-stimuli responsive supramolecular hydrogels based on host-guest inclusion complexation of a tadpole-shaped cyclodextrin derivative with the azobenzene dimer".POLYMER CHEMISTRY 8.26(2017):3901-3909.

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来源:化学研究所

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