Pd-Catalyzed Hydroxylation of Aryl Boronic Acids Using In Situ Generated Hydrogen Peroxide
文献类型：期刊论文
| 作者 | Yi, Hong1; Lei, Aiwen1,2 |
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | 2017-07-26 |
| 卷号 | 23期号:42页码:10023-10027 |
| 关键词 | Aerobic Oxidation Dioxygen Activation Hydrogen Peroxide Oxidative Coupling Palladium |
| 英文摘要 | Herein, we describe a benign and efficient palladium-catalyzed hydroxylation of aryl boronic acids under mild conditions, with in situ generated hydrogen peroxide from carbon monoxide, water, and oxygen. This novel procedure combines catalytic production of hydrogen peroxide with an aerobic oxidation process in a sole reaction system. This system shows good functional group tolerance and provides a benign and efficient access to a variety of functionalized phenols. Furthermore, the in situ generated hydroperoxide can be well used for triphenylphosphine oxidation, in which the TON is up to 194. Isotope labelling studies provide important mechanistic insights for this process. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38949]  |
| 专题 | 化学研究所_分子识别与功能实验室 |
| 作者单位 | 1.Wuhan Univ, IAS, Coll Chem & Mol Sci, Wuhan 430072, Hubei, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Mol Recognit & Funct, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yi, Hong,Lei, Aiwen. Pd-Catalyzed Hydroxylation of Aryl Boronic Acids Using In Situ Generated Hydrogen Peroxide[J]. CHEMISTRY-A EUROPEAN JOURNAL,2017,23(42):10023-10027. |
| APA | Yi, Hong,&Lei, Aiwen.(2017).Pd-Catalyzed Hydroxylation of Aryl Boronic Acids Using In Situ Generated Hydrogen Peroxide.CHEMISTRY-A EUROPEAN JOURNAL,23(42),10023-10027. |
| MLA | Yi, Hong,et al."Pd-Catalyzed Hydroxylation of Aryl Boronic Acids Using In Situ Generated Hydrogen Peroxide".CHEMISTRY-A EUROPEAN JOURNAL 23.42(2017):10023-10027. |
入库方式： OAI收割
来源：化学研究所
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