Subtle side-chain tuning on terminal groups of small molecule electron acceptors for efficient fullerene-free polymer solar cells
文献类型:期刊论文
作者 | Zhu, Jie1,2; Li, Sunsun2; Liu, Xiaoyu3; Yao, Huifeng2; Wang, Fenghao2; Zhang, Shaoqing3; Sun, Mingliang1; Hou, Jianhui2 |
刊名 | JOURNAL OF MATERIALS CHEMISTRY A
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出版日期 | 2017-08-07 |
卷号 | 5期号:29页码:15175-15182 |
英文摘要 | Four dithienoindaceno[1,2-b: 5,6-b']dithiophene (DT-IDT) based small molecules IT-O1, IT-O2, IT-O3 and IT-O4 with increasing alkoxyl chain length from methoxy to butoxy on the terminal-groups were synthesized to investigate the end-group side-chain effects on these acceptor-donor-acceptor-type small molecule electron acceptors. The optical absorption and energy levels of the four molecules, blend morphologies, carrier mobilities, and photovoltaic performances of the devices blended with the polymer PBDB-T are systematically investigated. Interestingly, both the solubility and electron mobility are enhanced for these materials with decrease in side chain length, which lead to ideal morphologies and balanced charge transport. Hence, increased J(sc) and FF, and thus distinctly higher PCEs of 11.6% were obtained from the PBDB-T:IT-O1-based devices. |
语种 | 英语 |
源URL | [http://ir.iccas.ac.cn/handle/121111/38950] ![]() |
专题 | 化学研究所_高分子物理与化学实验室 |
作者单位 | 1.Ocean Univ China, Inst Mat Sci & Engn, Qingdao 266100, Peoples R China 2.Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 3.Univ Sci & Technol Beijing, Sch Chem & Biol Engn, Beijing 100083, Peoples R China |
推荐引用方式 GB/T 7714 | Zhu, Jie,Li, Sunsun,Liu, Xiaoyu,et al. Subtle side-chain tuning on terminal groups of small molecule electron acceptors for efficient fullerene-free polymer solar cells[J]. JOURNAL OF MATERIALS CHEMISTRY A,2017,5(29):15175-15182. |
APA | Zhu, Jie.,Li, Sunsun.,Liu, Xiaoyu.,Yao, Huifeng.,Wang, Fenghao.,...&Hou, Jianhui.(2017).Subtle side-chain tuning on terminal groups of small molecule electron acceptors for efficient fullerene-free polymer solar cells.JOURNAL OF MATERIALS CHEMISTRY A,5(29),15175-15182. |
MLA | Zhu, Jie,et al."Subtle side-chain tuning on terminal groups of small molecule electron acceptors for efficient fullerene-free polymer solar cells".JOURNAL OF MATERIALS CHEMISTRY A 5.29(2017):15175-15182. |
入库方式: OAI收割
来源:化学研究所
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