中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Subtle side-chain tuning on terminal groups of small molecule electron acceptors for efficient fullerene-free polymer solar cells

文献类型:期刊论文

作者Zhu, Jie1,2; Li, Sunsun2; Liu, Xiaoyu3; Yao, Huifeng2; Wang, Fenghao2; Zhang, Shaoqing3; Sun, Mingliang1; Hou, Jianhui2
刊名JOURNAL OF MATERIALS CHEMISTRY A
出版日期2017-08-07
卷号5期号:29页码:15175-15182
英文摘要Four dithienoindaceno[1,2-b: 5,6-b']dithiophene (DT-IDT) based small molecules IT-O1, IT-O2, IT-O3 and IT-O4 with increasing alkoxyl chain length from methoxy to butoxy on the terminal-groups were synthesized to investigate the end-group side-chain effects on these acceptor-donor-acceptor-type small molecule electron acceptors. The optical absorption and energy levels of the four molecules, blend morphologies, carrier mobilities, and photovoltaic performances of the devices blended with the polymer PBDB-T are systematically investigated. Interestingly, both the solubility and electron mobility are enhanced for these materials with decrease in side chain length, which lead to ideal morphologies and balanced charge transport. Hence, increased J(sc) and FF, and thus distinctly higher PCEs of 11.6% were obtained from the PBDB-T:IT-O1-based devices.
语种英语
源URL[http://ir.iccas.ac.cn/handle/121111/38950]  
专题化学研究所_高分子物理与化学实验室
作者单位1.Ocean Univ China, Inst Mat Sci & Engn, Qingdao 266100, Peoples R China
2.Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
3.Univ Sci & Technol Beijing, Sch Chem & Biol Engn, Beijing 100083, Peoples R China
推荐引用方式
GB/T 7714
Zhu, Jie,Li, Sunsun,Liu, Xiaoyu,et al. Subtle side-chain tuning on terminal groups of small molecule electron acceptors for efficient fullerene-free polymer solar cells[J]. JOURNAL OF MATERIALS CHEMISTRY A,2017,5(29):15175-15182.
APA Zhu, Jie.,Li, Sunsun.,Liu, Xiaoyu.,Yao, Huifeng.,Wang, Fenghao.,...&Hou, Jianhui.(2017).Subtle side-chain tuning on terminal groups of small molecule electron acceptors for efficient fullerene-free polymer solar cells.JOURNAL OF MATERIALS CHEMISTRY A,5(29),15175-15182.
MLA Zhu, Jie,et al."Subtle side-chain tuning on terminal groups of small molecule electron acceptors for efficient fullerene-free polymer solar cells".JOURNAL OF MATERIALS CHEMISTRY A 5.29(2017):15175-15182.

入库方式: OAI收割

来源:化学研究所

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