Reductive Coupling of CO2, Primary Amine, and Aldehyde at Room Temperature: A Versatile Approach to Unsymmetrically N,N-Disubstituted Formamides
文献类型：期刊论文
| 作者 | Ke, Zhengang1,2; Hao, Leiduan1; Gao, Xiang1,2; Zhang, Hongye1; Zhao, Yanfei1; Yu, Bo1; Yang, Zhenzhen1; Chen, Yu1,2; Liu, Zhimin1,2 |
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | 2017-07-21 |
| 卷号 | 23期号:41页码:9721-9725 |
| 关键词 | Aldehydes Carbon Dioxide Formamides Primary Amines Reductive Coupling |
| 英文摘要 | We present a simple, metal-free, and versatile route to synthesize unsymmetrically N, N-disubstituted formamides (NNFAs) from CO2, primary amine, and aldehyde promoted by an ionic liquid (1-butyl-3-methylimidazolium chloride) at room temperature. This approach features wide scopes of amines and aldehydes, and various unsymmetrical NNFAs could be obtained in good to excellent yields. The ionic liquid can be reused for at least five runs without obvious activity loss. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/38956]  |
| 专题 | 化学研究所_胶体、界面与化学热力学实验室 |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Key Lab Colloid Interface & Thermodynam, Inst Chem,CAS Res Educ Ctr Excellence Mol Sci, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ke, Zhengang,Hao, Leiduan,Gao, Xiang,et al. Reductive Coupling of CO2, Primary Amine, and Aldehyde at Room Temperature: A Versatile Approach to Unsymmetrically N,N-Disubstituted Formamides[J]. CHEMISTRY-A EUROPEAN JOURNAL,2017,23(41):9721-9725. |
| APA | Ke, Zhengang.,Hao, Leiduan.,Gao, Xiang.,Zhang, Hongye.,Zhao, Yanfei.,...&Liu, Zhimin.(2017).Reductive Coupling of CO2, Primary Amine, and Aldehyde at Room Temperature: A Versatile Approach to Unsymmetrically N,N-Disubstituted Formamides.CHEMISTRY-A EUROPEAN JOURNAL,23(41),9721-9725. |
| MLA | Ke, Zhengang,et al."Reductive Coupling of CO2, Primary Amine, and Aldehyde at Room Temperature: A Versatile Approach to Unsymmetrically N,N-Disubstituted Formamides".CHEMISTRY-A EUROPEAN JOURNAL 23.41(2017):9721-9725. |
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来源：化学研究所
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