Direct Visualization of Nucleation and Growth Processes of Solid Electrolyte Interphase Film Using in Situ Atomic Force Microscopy
文献类型：期刊论文
| 作者 | Shi, Yang1,2,3; Yan, Hui-Juan1,2,3; Wen, Rui1,2,3; Wan, Li-Jun1,2,3 |
| 刊名 | ACS APPLIED MATERIALS & INTERFACES
 |
| 出版日期 | 2017-07-05 |
| 卷号 | 9期号:26页码:22063-22067 |
| 关键词 | In Situ Atomic Force Microscopy Li-ion Battery Solid Electrolyte Interphase Ionic Liquid Interface |
| 英文摘要 | An understanding of the formation mechanism of solid electrolyte interphase (SEI) film at the nanoscale is paramount because it is one of the key issues at interfaces in lithium-ion batteries (LIBs). Herein, we explored the nucleation, growth, and formation of SEI film on highly oriented pyrolytic graphite (HOPG) substrate in ionic liquid-based electrolytes 1-butyl-1-methyl-pyrrolidinium bis(fluorosulfonyl)imide ([BMP](+)[FSI](-)) and 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide ([BMP](+)[TFSI](-)) by in situ atomic force microscopy (AFM) and found that the types of anions have significant influence on the structure of the formed SEI. In [BMP](+)[FSI](-) containing LiFSI, a compact and thin SEI film prefers to grow in the plane of HOPG substrate, while a rough and loose film tends to form in [BMP](+)[TFSI](-) containing LiTFSI. On the basis of in situ AFM observations, the relationship between the SEI structure and the electrochemical performance was clarified. |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/39007]  |
| 专题 | 化学研究所_分子纳米结构与纳米技术实验室 |
| 作者单位 | 1.Chinese Acad Sci, Key Lab Mol Nanostruct & Nanotechnol, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Inst Chem, CAS Res Educ Ctr Excellence Mol Sci, Beijing Natl Lab Mol Sci, Beijing 100049, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shi, Yang,Yan, Hui-Juan,Wen, Rui,et al. Direct Visualization of Nucleation and Growth Processes of Solid Electrolyte Interphase Film Using in Situ Atomic Force Microscopy[J]. ACS APPLIED MATERIALS & INTERFACES,2017,9(26):22063-22067. |
| APA | Shi, Yang,Yan, Hui-Juan,Wen, Rui,&Wan, Li-Jun.(2017).Direct Visualization of Nucleation and Growth Processes of Solid Electrolyte Interphase Film Using in Situ Atomic Force Microscopy.ACS APPLIED MATERIALS & INTERFACES,9(26),22063-22067. |
| MLA | Shi, Yang,et al."Direct Visualization of Nucleation and Growth Processes of Solid Electrolyte Interphase Film Using in Situ Atomic Force Microscopy".ACS APPLIED MATERIALS & INTERFACES 9.26(2017):22063-22067. |
入库方式： OAI收割
来源：化学研究所
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