Recyclable polybutadiene elastomer based on dynamic imine bond
文献类型：期刊论文
| 作者 | Zhang, Huan1,2; Wang, Dong1,2; Liu, Wenxing1,2; Li, Pengchong1; Liu, Jiajian1,2; Liu, Chenyang1,2; Zhang, Jiawei3; Zhao, Ning1; Xu, Jian1,2 |
| 刊名 | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
 |
| 出版日期 | 2017-06-15 |
| 卷号 | 55期号:12页码:2011-2018 |
| 关键词 | Dynamic Imine Bond Polybutadiene Recyclable Solvent Resistance |
| 英文摘要 | Catalyst-free recyclable polybutadiene (PB) elastomer cross-linked by dynamic imine bonds is prepared by the reaction between amine functionalized PB and aldehyde cross-linkers. The dynamic nature of imine bond is investigated by rheometry and creep-recovery experiments. The cross-linking degrees are regulated by incorporating different amount of aldehyde, and their influence on the cross-linked elastomers is investigated in detail. The temperature-induced imine exchange reactions enable recycling of the cross-linked PB elastomers and their mechanical properties are almost unchanged after several cycles. It is important to note that the elastomers also show excellent solvent resistance even at high temperature. The good mechanical properties, solvent resistance and recycling ability of the resultant PB elastomer demonstrate the superiority of the imine bonds in the design of recyclable polymers. (c) 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017, 55, 2011-2018 |
| 语种 | 英语 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/39017]  |
| 专题 | 化学研究所_高分子物理与化学实验室 |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Lab Polymer Phys & Chem, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Div Polymer & Composite Mat, Ningbo 315201, Zhejiang, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Huan,Wang, Dong,Liu, Wenxing,et al. Recyclable polybutadiene elastomer based on dynamic imine bond[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2017,55(12):2011-2018. |
| APA | Zhang, Huan.,Wang, Dong.,Liu, Wenxing.,Li, Pengchong.,Liu, Jiajian.,...&Xu, Jian.(2017).Recyclable polybutadiene elastomer based on dynamic imine bond.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,55(12),2011-2018. |
| MLA | Zhang, Huan,et al."Recyclable polybutadiene elastomer based on dynamic imine bond".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 55.12(2017):2011-2018. |
入库方式： OAI收割
来源：化学研究所
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